Etrimfos

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Names

[ CAS No. ]:
38260-54-7

[ Name ]:
Etrimfos

[Synonym ]:
O,O-dimethyl O-6-ethoxy-2-ethylpyrimidin-4-yl phosphorothioate
Satisfar DP-2
Etrimphos
(6-ethoxy-2-ethylpyrimidin-4-yl)oxy-dimethoxy-sulfanylidene-λ<sup>5</sup>-phosphane
O-(6-ethoxy-2-ethyl-4-pyrimidinyl) O,O-dimethyl phosphorothioate
Ekamet G
MFCD00055516
Satisfar
Ekamet ULV
Ekamet
O-6-ethoxy-2-ethylpyrimidin-4-yl O,O-dimethyl phosphorothioate
ETRIMFOS
EINECS 253-855-9
Satisfar LS 5
Caswell No. 365AAA
O-(6-ethoxy-2-ethylpyrimidin-4-yl) O,O-dimethyl phosphorothioate
Satisfar LS 3

Chemical & Physical Properties

[ Density]:
1.246g/cm3

[ Boiling Point ]:
352.6ºC at 760mmHg

[ Melting Point ]:
-3.35℃

[ Molecular Formula ]:
C10H17N2O4PS

[ Molecular Weight ]:
292.29200

[ Flash Point ]:
167ºC

[ Exact Mass ]:
292.06500

[ PSA ]:
104.60000

[ LogP ]:
2.98440

[ Appearance of Characters ]:
liquid

[ Index of Refraction ]:
1.528

[ Storage condition ]:
APPROX 4°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TF8350000
CHEMICAL NAME :
Phosphorothioic acid, O,O-dimethyl O-(6-ethoxy-2-ethyl-4-pyrimidinyl) ester
CAS REGISTRY NUMBER :
38260-54-7
LAST UPDATED :
199204
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C10-H17-N2-O4-P-S
MOLECULAR WEIGHT :
292.32
WISWESSER LINE NOTATION :
T6N CNJ B2 DOPS&O1&O1 FO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,137,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,358,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
437 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBICDJ Proceedings of the British Insecticide and Fungicide Conference. V-8, 1961-75. For Publisher information, See PBCDDQ Volume(issue)/page/year: 2,675,1975
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,358,1991

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H311-H410

[ Precautionary Statements ]:
P273-P280-P301 + P312 + P330-P302 + P352 + P312-P391-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
22-50/53

[ Safety Phrases ]:
60-61

[ RIDADR ]:
UN3082 9/PG 3

[ RTECS ]:
TF8350000

[ HS Code ]:
2933599011

Synthetic Route

Precursor & DownStream

Precursor

  • Dimethyl chlorothiophosphate

DownStream

Customs

[ HS Code ]: 2933599011

[ Summary ]:
2933599011 o-(2-(diethylamino)-6-methylpyrimidin-4-yl) o,o-dimethyl phosphorothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

Articles

[Determination of the ekamet content of vegetables and apples by thin-layer chromatography].

Vopr. Pitan. (3) , 70-1, (1984)

Pesticide confirmation by triple stage quadrupole mass spectrometry: etrimfos and dimethoate.

J. Assoc. Off. Anal. Chem. 70(5) , 858-62, (1987)

The production of a protonated molecular ion, MH+, for a pesticide under investigation is often preferred for primary identification purposes. However, the lack of fragment ions under such chemical io...


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Related Compounds

  • etrimfos alcohol metabolite
  • (Z)-2-(benzofuran-2-ylmethylene)-7-((diethylamino)methyl)-6-hydroxy-4-methylbenzofuran-3(2H)-one
  • N-[4-(acetylamino)phenyl]-2-(2-oxo-3,4-dihydro-2H-1,4-benzoxazin-3-yl)acetamide
  • 2-{1-[(2-fluorophenyl)sulfonyl]pyrrolidin-2-yl}-1H-benzimidazole
  • (2Z)-2-(4-bromobenzylidene)-3-oxo-2,3-dihydro-1-benzofuran-6-yl 4-methoxybenzenesulfonate
  • 1-(5-(2-hydroxyphenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-2-(piperidin-1-yl)ethanone
  • 1-(Furan-2-ylmethyl)cyclopropane-1-carboxylic acid
  • 2,3-Dihydro-7-methoxy-1-oxo-1H-indene-2-acetic acid
  • ethyl 5-methoxy-2,3-dihydro-1H-indene-2-carboxylate
  • Ethyl 4-fluoro-7-hydroxy-indan-1-one-2-carboxylate
  • 1,2-Diamino-1-phenylpropane
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