2,2'-bis(bromomethyl)-1,1'-biphenyl

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Names

[ CAS No. ]:
38274-14-5

[ Name ]:
2,2'-bis(bromomethyl)-1,1'-biphenyl

[Synonym ]:
2,2'-dibromomethyl-1,1'-biphenyl
MFCD00074910

Chemical & Physical Properties

[ Density]:
1.591g/cm3

[ Boiling Point ]:
421.3ºC at 760mmHg

[ Melting Point ]:
90-92ºC(lit.)

[ Molecular Formula ]:
C14H12Br2

[ Molecular Weight ]:
340.05300

[ Flash Point ]:
244.1ºC

[ Exact Mass ]:
337.93100

[ LogP ]:
5.14340

[ Index of Refraction ]:
1.631

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
34-36/37

[ Safety Phrases ]:
26-27-28-36/37/39-45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • [1,1'-Biphenyl]-2,2'-dimethanol
  • Phosphorus tribromide
  • DIMETHYLBIPHENYL
  • biphenyl-2,2'-dicarboxylic acid
  • [1,1'-Biphenyl]-2,2'-dicarboxylicacid, 2,2'-dimethyl ester
  • Anthranilic acid
  • m-tolidine
  • 2,2'-Dibromobiphenyl
  • DIETHYL BIPHENYL 2,2'-DICARBOXYLATE

DownStream

  • 6-methyl-5,7-dihydrobenzo[d][2]benzothiepin-6-ium,iodide
  • 6,6-dioxo-5,7-dihydrobenzo[d][2]benzothiepine-5,7-dicarboxylic acid
  • 5-N,5-N,7-N,7-N-tetramethyl-6,6-dioxo-5,7-dihydrobenzo[d][2]benzothiepine-5,7-dicarboxamide
  • 6-allyl-6,7-dihydro-5H-dibenz[c,e]azepine
  • 9-methylphenanthrene
  • 9H FLUORENE
  • DIMETHYLBIPHENYL
  • 9,10-Dihydrophenanthrene
  • 9-methylfluorene

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Separation and optical resolution of a pair of atrop diastereomers of the octahedral rhodium(III) complex with a nine-membered S,S-chelate ring.

Inorg. Chem. 47(17) , 7450-2, (2008)

Treatment of fac-[Rh(aet) 3] (aet = 2-aminoethanethiolate) with 2,2'-bis(bromomethyl)-1,1'-biphenyl gave a mononuclear rhodium(III) complex with a nine-membered S, S-chelate ring, fac-[Rh(aet)(L)] (2+...

Novel α, α-disubstituted a-aminoacids with axial dissymmetry and their N-or C-protected derivatives. Mazaleyrat J-P, et al.

Tetrahedron Asymmetry 8(4) , 619-31, (1997)


More Articles

Related Compounds

  • 2,2'-bis(bromomethyl)-1,1'-binaphthyl
  • 2,2'-bis(bromomethyl)-1,1'-binaphthyl
  • 1-(bromomethyl)-2-[2-(bromomethyl)-6-methyl-phenyl]-3-methyl-benzene
  • 1-(bromomethyl)-2-[2-(bromomethyl)phenoxy]benzene
  • 2,2'-BIS(TRIFLUOROMETHANESULFONYLOXY)-1,1'-BIPHENYL
  • 2,2'-Bis(Trifluoromethyl)-1,1'-Biphenyl