1,1-bis(phenylsulfonyl)ethylene

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Names

[ Name ]:
1,1-bis(phenylsulfonyl)ethylene

[Synonym ]:
(ethene-1,1-diyldisulfonyl)dibenzene
1,1-Bis(benzenesulfonyl)ethylene
1,1-bis-(phenylsulfonyl)ethylene
1,1-bis(phenylsulphonyl)ethylene
1,1-bis(benzenesulphonyl)ethylene
1,1-Bis<benzenesulfonyl>ethene

Chemical & Physical Properties

[ Density]:
1.347g/cm3

[ Boiling Point ]:
567.9ºC at 760 mmHg

[ Melting Point ]:
124-126ºC

[ Molecular Formula ]:
C₁₄H₁₂O₄S₂

[ Molecular Weight ]:
308.37300

[ Flash Point ]:
383.9ºC

[ Exact Mass ]:
308.01800

[ PSA ]:
85.04000

[ LogP ]:
4.56700

[ Index of Refraction ]:
1.596

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Formaldehyde
Bis(phenylsulfonyl)methane
1-(2,2-bis(phenylsulfonyl)ethyl)piperidine
(Methylenebis(thio))bisbenzene
Thiophenol

DownStream

4,4'-Methylenedimorpholine
Bis(phenylsulfonyl)methane
1,3,3-tris(benzenesulfonyl)propylsulfonylbenzene
4-(2,2-bis(phenylsulfonyl)ethyl)morpholine
DIPIPERIDINOMETHANE
1-(2,2-bis(phenylsulfonyl)ethyl)piperidine
Benzene,1,1'-[(1E)-1,2-ethenediylbis(sulfonyl)]bis-
N,N'-dioctadecylmethanediamine
Methanediamine,N,N,N',N'-tetraethyl-
4,4-bis(benzenesulfonyl)-1-phenylbutan-1-one

Articles

Enantioselective organocatalytic addition of oxazolones to 1,1-bis(phenylsulfonyl)ethylene: a convenient asymmetric synthesis of quaternary alpha-amino acids.

Chemistry 16(18) , 5354-61, (2010)

A new, easy, and highly enantioselective method for the synthesis of quaternary alpha-alkyl-alpha-amino acids based on organocatalysis is reported. The addition of oxazolones to 1,1-bis(phenylsulfonyl...

O. De Lucchi et al.

Tetrahedron Lett. 25 , 3643, (1984)

O. De Lucchi, L. Pasquato

Tetrahedron 44 , 6755, (1988)

2,2,2-tricarbonyl-1,1-bis(ethylene)-mu-(eta(5),eta(5)-fulvalene)-2-methylrhodiumtungsten
3,3-bis(benzenesulfonyl)propylbenzene
2,2-bis(benzenesulfonyl)ethenylbenzene
1,1-bis(trichlorosilylmethyl)ethylene
1,1-bis(trichlorosilyl)ethylene
1,1-bis(trimethylgermyl)ethylene
(Z)-N-(2,4-difluorophenyl)-8-methoxy-2-(2-tosylhydrazono)-2H-chromene-3-carboxamide
N-(1-((4-fluorophenyl)sulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl)-2-methylpropane-1-sulfonamide
2-Amino-3-(4-fluoro-2-methoxyphenyl)propanoic acid
8-Fluoro-N-2-pyrazinyl-2-quinolinamine
3-[[[3-(4-Aminophenyl)-4-oxo-4H-1-benzopyran-7-yl]oxy]methyl]benzoic acid
Ethyl 6-[(4-chlorobenzenesulfonyl)methyl]-4-(3-fluorophenyl)-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
Ethyl 4-(2-methoxyphenyl)-6-[(4-methylbenzenesulfonyl)methyl]-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
Ethyl 6-[(4-methylbenzenesulfonyl)methyl]-4-(2-methylphenyl)-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
Ethyl 6-[(3,4-dimethylbenzenesulfonyl)methyl]-4-(2-methoxyphenyl)-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
Ethyl 6-[(4-fluorobenzenesulfonyl)methyl]-4-(4-fluorophenyl)-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate

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