a,a-Difluoroacetophenone

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Names

[ CAS No. ]:
395-01-7

[ Name ]:
a,a-Difluoroacetophenone

[Synonym ]:
2,2-DIFLUORO-1,3-DIMETHYLBENZIMIDAZOLIDINE
A,A-DIFLUOROACETOPHENONE
2,2-difluoro-1-phenylethan-1one
MFCD06246879
2,2-DIFLUORO-1-PHENYLETHANONE
2,2-Difluoroacetophenone
2,2-difluorophenylethan-1-one

Chemical & Physical Properties

[ Density]:
1.18g/cm3

[ Boiling Point ]:
53-54ºC/12mm

[ Melting Point ]:
48-50ºC

[ Molecular Formula ]:
C8H6F2O

[ Molecular Weight ]:
156.12900

[ Flash Point ]:
71.9ºC

[ Exact Mass ]:
156.03900

[ PSA ]:
17.07000

[ LogP ]:
2.13440

[ Index of Refraction ]:
1.4955

[ Storage condition ]:
2-8°C

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Difluoroacetonitrile
  • benzene
  • Ethanone,2,2-dichloro-1-phenyl-
  • 1-phenyl-2,2,-difluoroethanol
  • Chlorodifluoroacetophenone
  • (2,2-difluoro-1-phenylethenyl) diethyl phosphate
  • Benzenemethanol, α-methylene-, 1-acetate
  • Phenylacetylene
  • (2,2-difluoro-1-phenylethenoxy)-trimethylsilane
  • 2,2-Difluoroacetyl chloride

DownStream

  • (DIFLUOROMETHYL)BENZENE
  • alpha,alpha,alpha,alpha',alpha'-pentafluoro-o-xylene
  • phenyl 2,2-difluoroacetate
  • (1S,2R)-FMOC-2-AMINOCYCLOHEX-3-ENE-CARBOXYLIC ACID
  • 2,2-difluoro-1-phenylethanamine
  • 1-Chloro-4-(difluoromethyl)benzene
  • 2,2-difluoroethylbenzene

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • a,a-Dimethylphenethyl butyrate
  • 3-[(A,A,A-TRIFLUORO-M-TOLYL)OXY]-PYRROLIDINE HYDROCHLORIDE
  • Benzeneethanol, a,a-diethyl-b-(methylamino)-, hydrochloride (1:1)
  • Benzeneethanol, a,a-diethyl-b-(methylimino)-
  • Benzeneethanol, a,a-diethyl-b-methoxy-, 1-(4-nitrobenzoate)
  • Benzenemethanol, a,a-dicyclopropyl-4-methoxy-
  • [1-(4-Fluorophenyl)-2,2-dimethylcyclopropyl]methanol
  • [1-(4-Chlorophenyl)-2,2-dimethylcyclopropyl]methanol
  • O-[2-(4-fluoro-2-methylphenyl)ethyl]hydroxylamine
  • [1-(4-Bromophenyl)-2,2-dimethylcyclopropyl]methanol
  • 2-(2,2-Dimethylthiomorpholin-4-yl)-N-(2-hydroxyethyl)acetamide
  • 1-(2,2-Dimethylthiomorpholin-4-yl)propan-2-ol
  • 4-(3-Bromopropyl)-2,2-dimethylthiomorpholine
  • 4-(3-Chloro-2-methylpropyl)-2,2-dimethylthiomorpholine
  • 4-(4-Chlorobutyl)-2,2-dimethylthiomorpholine
  • 1-Bromo-3-(2,2-dimethylthiomorpholin-4-yl)propan-2-ol
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