2-Nitrobenzylbromide

Names

[ Name ]:
2-Nitrobenzylbromide

[Synonym ]:
1-(Bromomethyl)-2-nitrobenzene
o-nitrobenzyl bromide
nitrobenzyl bromide
MFCD00007184
EINECS 223-558-9
Benzene, 1-(bromomethyl)-2-nitro-
α-Bromo-2-nitrotoluene
2-Nitrobenzylbromide

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
275.2±15.0 °C at 760 mmHg

[ Melting Point ]:
44-46 °C(lit.)

[ Molecular Formula ]:
C₇H₆BrNO₂

[ Molecular Weight ]:
216.032

[ Flash Point ]:
120.2±20.4 °C

[ Exact Mass ]:
214.958176

[ PSA ]:
45.82000

[ LogP ]:
2.65

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.612

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29049085

Precursor & DownStream

Precursor

2-Nitrotoluene
2-Nitrobenzyl alcohol
Ammonium acetate
(2-nitrophenyl)methyl thiocyanate
2-Nitrobenzyl chloride
Carbon tetrachloride
N-Bromosuccinimide
Benzoyl peroxide

DownStream

9-[(2-nitrophenyl)methyl]purin-6-amine
2-AMINOBENZYLAMINE
1-(2-Nitrobenzyl)-1H-pyrrole-2-carbaldehyde
1-methyl-4-[(2-nitrophenyl)methyl]piperazine
1-TERT-BUTYL 3-ETHYL 3-(2-NITROBENZYL)PIPERIDINE-1,3-DICARBOXYLATE
3,4-Dihydroquinolin-2(1H)-one
triethylammonium bromide
2-Methylindole
2-Phenylindole
1-(iodomethyl)-2-nitrobenzene

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Distributed Drug Discovery, Part 2: global rehearsal of alkylating agents for the synthesis of resin-bound unnatural amino acids and virtual D(3) catalog construction.

J. Comb. Chem. 11 , 14-33, (2009)

Distributed Drug Discovery (D(3)) proposes solving large drug discovery problems by breaking them into smaller units for processing at multiple sites. A key component of the synthetic and computationa...

A photolabile hydrogel for guided three-dimensional cell growth and migration.

Nat. Mater. 3(4) , 249-53, (2004)

Tissue engineering aims to replace, repair or regenerate tissue/organ function, by delivering signalling molecules and cells on a three-dimensional (3D) biomaterials scaffold that supports cell infilt...

Caged cysteine and thiophosphoryl peptides.

FEBS Lett. 405(1) , 81-5, (1997)

Photoreleasable molecules are important in studies of various biological phenomena, especially cell signaling. Here we report a generally applicable approach for 'caging' unprotected cysteine-containi...