Methyl (R)-(-)-3-hydroxybutyrate

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Names

[ CAS No. ]:
3976-69-0

[ Name ]:
Methyl (R)-(-)-3-hydroxybutyrate

[Synonym ]:
(R)-3-Hydroxy-n-butyric acid methyl ester
EINECS 223-610-0
(R)-3-Hydroxybutyric acid methyl ester
Methyl (3R)-3-hydroxybutanoate
(R)-(-)-3-Hydroxy-n-butyric acid methyl ester
QY1&1VO1 &&R Form
(R)-(-)-3-Hydroxybutyric acid methyl ester
Methyl (R)-3-hydroxybutanoate
Butanoic acid, 3-hydroxy-, methyl ester, (3R)-
MFCD00063289
Methyl (R)-3-Hydroxybutyrate
(R)-Methyl 3-hydroxybutanoate
Methyl(R)-(-)-3-hydroxybutyrate

Chemical & Physical Properties

[ Density]:
1.055

[ Boiling Point ]:
161.9±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H10O3

[ Molecular Weight ]:
118.131

[ Flash Point ]:
71.7±0.0 °C

[ Exact Mass ]:
118.062996

[ PSA ]:
46.53000

[ LogP ]:
-0.55

[ Vapour Pressure ]:
0.8±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.420

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2918199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl acetoacetate
  • Ethyl acetoacetate
  • Methanol
  • carbon monoxide
  • (R)-(+)-Propylene oxide
  • diazomethane
  • (R)-3-Hydroxybutanoic acid
  • (R)-methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate
  • tert-Butyl acetoacetate
  • Ethyl (R)-3-hydroxybutyrate

DownStream

  • methyl (3R)-3-[(4-methoxyphenyl)methoxy]butanoate
  • D-Allothreonine
  • L-Threonine
  • (R)-3-Hydroxybutanoic acid
  • Methanol
  • anhydrodihydroartemisinin
  • Artemether
  • (R)-methyl 3-(((3R,5aS,6R,8aS,9R,10S,12R,12aR)-3,6,9-trimethyldecahydro-3H-3,12-epoxy[1,2]dioxepino[4,3-i]isochromen-10-yl)oxy)butanoate
  • (S)-METHYL 3-(THIOPHEN-2-YLTHIO)BUTANOATE
  • (R)-(-)-1,3-Butanediol

Customs

[ HS Code ]: 2918199090

[ Summary ]:
2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

A novel carbonyl reductase with anti-Prelog stereospecificity from Acetobacter sp. CCTCC M209061: purification and characterization.

PLoS ONE 9(4) , e94543, (2014)

A novel carbonyl reductase (AcCR) catalyzing the asymmetric reduction of ketones to enantiopure alcohols with anti-Prelog stereoselectivity was found in Acetobacter sp. CCTCC M209061 and enriched 27.5...

First total synthesis of grahamimycin A.

J. Org. Chem. 65 , 7221, (2000)

Efficient asymmetric synthesis of radicicol dimethyl ether: a novel application of ring-forming olefin metathesis.

Org. Lett. 2 , 3127, (2000)

A concise, stereospecific synthesis of radicicol dimethyl ether is presented. The strategy relies on a convergent three-stage assembly of the 14-membered lactone which has, as a key transformation, a ...


More Articles

Related Compounds

  • Methyl (R)-3-amino-3-(4-ethylphenyl)propanoate hydrochloride
  • METHYL (R)-3-(4-FLUOROPHENYL)-2-HYDROXYPROPIONATE
  • Methyl (R)-3-amino-3-(2-chloropyridin-4-yl)propanoate dihydrochloride
  • methyl (r)-3-phenylbutyrate
  • Methyl (R)-3-amino-3-(3-chloro-5-methoxyphenyl)propanoate hydrochloride
  • Methyl (R)-3-amino-3-(4-bromo-2-methylphenyl)propanoate hydrochloride
  • 1-Cyclopropyl-2,2-difluoro-3-(methylamino)propan-1-ol hydrochloride
  • 1-Cyclopentyl-2,2-difluoropropane-1,3-diol
  • rac-(2R,6S)-1-acetyl-6-(4-methoxyphenyl)piperidine-2-carboxylic acid
  • 3-Amino-1-cyclopentyl-2,2-difluoropropan-1-ol hydrochloride
  • 1-Cyclopentyl-2,2-difluoro-3-(methylamino)propan-1-ol hydrochloride
  • 3-(2,3-Dimethylphenyl)-3-{[(prop-2-en-1-yloxy)carbonyl]amino}propanoic acid
  • Tert-butyl 7-(bromomethyl)-1,4-oxazepane-4-carboxylate
  • 1-(3-Bromophenyl)-3-hydroxy-4,4-dimethylpyrrolidin-2-one
  • 1-(4-Fluorophenyl)-3-hydroxy-4,4-dimethylpyrrolidin-2-one
  • 1-(4-Fluorophenyl)-4,4-dimethylpyrrolidin-3-ol
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