(3-bromophenylethynyl)trimethylsilane

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Names

[ CAS No. ]:
3989-13-7

[ Name ]:
(3-bromophenylethynyl)trimethylsilane

[Synonym ]:
[(3-bromophenyl)ethynyl](trimethyl)silane
meta-bromophenyltrimethylsilylacetylene
(2-(3-bromophenyl)ethynyl)trimethylsilane
MFCD01863664

Chemical & Physical Properties

[ Density]:
1.189 g/mL at 25ºC(lit.)

[ Boiling Point ]:
80ºC0.2 mm Hg(lit.)

[ Molecular Formula ]:
C11H13BrSi

[ Molecular Weight ]:
253.21000

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
251.99700

[ LogP ]:
3.67800

[ Index of Refraction ]:
n20/D 1.555(lit.)

MSDS

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Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

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Precursor & DownStream

Precursor

  • 1-Bromo-3-iodobenzene
  • TMS-acetylene
  • 1,3-Dibromobenzene
  • 1,2-Dibromobenzene
  • Chlorotrimethylsilane
  • 3'-Bromophenyl acetylene

DownStream

  • 3'-Bromophenyl acetylene

Articles

Enantioselective synthesis of both enantiomers of various propargylic alcohols by use of two oxidoreductases. Schubert T, et al.

European J. Org. Chem. 2001(22) , 4181-4187, (2001)


More Articles

Related Compounds

  • (4-BROMOPHENYLETHYNYL)TRIMETHYLSILANE
  • (2-bromophenylethynyl)trimethylsilane
  • [(4-Bromophenyl)ethynyl](trimethyl)silane
  • (3-methoxybenzyl)trimethylsilane
  • (3-chlorothiobenzoyl)trimethylsilane
  • (3-fluorophenyl)-trimethylsilane