(3-bromophenylethynyl)trimethylsilane

Suppliers

Names

[ Name ]:
(3-bromophenylethynyl)trimethylsilane

[Synonym ]:
[(3-bromophenyl)ethynyl](trimethyl)silane
meta-bromophenyltrimethylsilylacetylene
(2-(3-bromophenyl)ethynyl)trimethylsilane
MFCD01863664

Chemical & Physical Properties

[ Density]:
1.189 g/mL at 25ºC(lit.)

[ Boiling Point ]:
80ºC0.2 mm Hg(lit.)

[ Molecular Formula ]:
C₁₁H₁₃BrSi

[ Molecular Weight ]:
253.21000

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
251.99700

[ LogP ]:
3.67800

[ Index of Refraction ]:
n20/D 1.555(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Bromo-3-iodobenzene
TMS-acetylene
1,3-Dibromobenzene
1,2-Dibromobenzene
Chlorotrimethylsilane
3'-Bromophenyl acetylene

DownStream

Articles

Enantioselective synthesis of both enantiomers of various propargylic alcohols by use of two oxidoreductases. Schubert T, et al.

European J. Org. Chem. 2001(22) , 4181-4187, (2001)

(4-BROMOPHENYLETHYNYL)TRIMETHYLSILANE
(2-bromophenylethynyl)trimethylsilane
[(4-Bromophenyl)ethynyl](trimethyl)silane
(3-methoxybenzyl)trimethylsilane
(3-chlorothiobenzoyl)trimethylsilane
(3-fluorophenyl)-trimethylsilane
2-({1-[2-Oxo-1-(2,2,2-trifluoroethyl)pyrrolidin-3-yl]piperidin-4-yl}methoxy)pyridine-4-carbonitrile
4-[(2-Methyl-1,3-oxazol-4-yl)methyl]-2-(piperidine-1-carbonyl)morpholine
4-[(5-Methyl-1,2-oxazol-3-yl)methyl]-2-(piperidine-1-carbonyl)morpholine
5-{2,5-Dimethylpyrazolo[1,5-a]pyrimidin-7-yl}-octahydropyrrolo[3,4-c]pyrrole-1,3-dione
N,4,6-trimethyl-N-[1-(pyrazin-2-yl)azetidin-3-yl]pyrimidin-2-amine
N-Methyl-N-(1-pyridin-2-ylazetidin-3-yl)-1,3-thiazole-4-carboxamide
4-(2-Cyclopropyl-6-methylpyrimidin-4-yl)-2-(piperidine-1-carbonyl)morpholine
4-[(3,5-Dimethyl-1,2-oxazol-4-yl)methyl]-2-(piperidine-1-carbonyl)morpholine
1-[4-(Trifluoromethyl)-1,3-benzothiazol-2-yl]piperidine-4-carboxamide
2-methoxy-N-{[1-(2,2,2-trifluoroethyl)piperidin-4-yl]methyl}benzamide

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