(E)-1,2-Cyclopropanedicarboxylic acid diethyl ester

Names

[ Name ]:
(E)-1,2-Cyclopropanedicarboxylic acid diethyl ester

[Synonym ]:
Diethyltrans-cyclopropane-1,2-dicarboxylate
diethyl (1R,2R)-cyclopropane-1,2-dicarboxylate
trans-Diethyl cyclopropane-1,2-dicarboxylate
MFCD00001286

Chemical & Physical Properties

[ Density]:
1.153g/cm3

[ Boiling Point ]:
246.3ºC at 760mmHg

[ Molecular Formula ]:
C₉H₁₄O₄

[ Molecular Weight ]:
186.20500

[ Flash Point ]:
98.3ºC

[ Exact Mass ]:
186.08900

[ PSA ]:
52.60000

[ LogP ]:
0.74870

[ Index of Refraction ]:
n20/D 1.441(lit.)

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triethyl phosphonoacetate
Ethyl 2,3-epoxypropanoate
ethyl chloroacetate
Ethyl acrylate TOP1 supplier
(+/-)-trans-1,2-Cyclopropanedicarboxylic acid
Dibromomethane
1,1,2-Cyclopropanetricarboxylic acid, triethyl ester
ethyl (dimethyl-λ4-sulfanylidene)acetate
Trimethylsulfoxonium iodide

DownStream

(1s,2s)-cyclopropane-1,2-dicarboxylic Acid
Dimethyl (1R,2R)-1,2-cyclopropanedicarboxylate
ethyl (1R,2R)-2-acetylcyclopropane-1-carboxylate
1,2-Cyclopropanedicarboxylicacid, 1-ethyl ester, (1R,2R)-rel-
(+/-)-trans-1,2-Cyclopropanedicarboxylic acid

Customs

[ HS Code ]: 2917209090

[ Summary ]:
2917209090 other cyclanic, cyclenic or cyclotherpenic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Cyclopropanation of dimethyl fumarate and maleate with gem-dihalides catalyzed by Co (0)-or Ni (0)-complex and zinc. Kanai H, et al.

Bull. Chem. Soc. Jpn. 56(6) , 1592-97, (1983)

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