Trimethylsilyl trifluoroacetate

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Names

[ CAS No. ]:
400-53-3

[ Name ]:
Trimethylsilyl trifluoroacetate

[Synonym ]:
MFCD00000413
Acetic acid, 2,2,2-trifluoro-, trimethylsilyl ester
Trifluoroacetic Acid Trimethylsilyl Ester
trimethylsilyl 2,2,2-trifluoroacetate
Acetic acid, trifluoro-, trimethylsilyl ester
EINECS 206-923-7
Trimethylsilyl trifluoroacetate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
89.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H9F3O2Si

[ Molecular Weight ]:
186.204

[ Flash Point ]:
-0.6±0.0 °C

[ Exact Mass ]:
186.032394

[ PSA ]:
26.30000

[ LogP ]:
2.76

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
59.7±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.353

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;C: Corrosive;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Bis(trimethylsilyl) sulfate
  • Sodium perfluoroacetate
  • Trifluoroacetyl chloride
  • POTASSIUM TRIMETHYLSILANOLATE
  • diisopropyl(carboethoxyfluoromethyl)phosphonate
  • Chlorotrimethylsilane
  • trifluoroacetic acid
  • 1-(Trimethylsilyl)piperidine-2-one
  • Dimethylchloromethyltrifluoroacetoxysilane

DownStream

  • BUTOXYTRIMETHYLSILANE
  • Hexamethyldisiloxane
  • Acetic acid,2,2,2-trifluoro-, butyl ester
  • Ethyl trifluoroacetoacetate
  • Fluoro(trimethyl)silane
  • boron tris(trifluoroacetate)
  • PHENYL TRIFLUOROACETATE
  • Tetrakis(trimethylsilyl) orthosilicate
  • 7,7-difluorobicyclo[4.1.0]heptane
  • Tetrafluoroethylene

Articles

M. Demuth et al.

Helv. Chim. Acta 64 , 2759, (1981)

Y. Tanabe et al.

J. Org. Chem. 53 , 4582, (1988)


More Articles

Related Compounds

  • trimethylsilyl trifluoroacetate phenylhydrazone
  • (Trimethylsilyl)(p-tert-butylphenyl)-methanol
  • trimethylsilyl 4,4,4-trifluoro-3-(trimethylsilylamino)butanoate
  • (trimethylsilyl)sodium
  • Trimethylsilyl-10-undecenoate
  • Trimethylsilyl O,O'-bis(trimethylsilyl)vanilmandelate
  • 2-(1H-indol-3-yl)-N-((3-(1-methyl-1H-pyrrol-2-yl)-1,2,4-oxadiazol-5-yl)methyl)-2-oxoacetamide
  • N-(4-methyl-2-(N-((3-(1-methyl-1H-pyrrol-2-yl)-1,2,4-oxadiazol-5-yl)methyl)sulfamoyl)phenyl)acetamide
  • N-((3-(1-methyl-1H-pyrrol-2-yl)-1,2,4-oxadiazol-5-yl)methyl)tetrahydrofuran-2-carboxamide
  • 2-(5-Methylpyridazin-3-yl)propan-2-ol
  • 1-(2-methoxyphenyl)-5-methyl-N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)-1H-1,2,3-triazole-4-carboxamide
  • N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)-3-(3-(o-tolyl)-1,2,4-oxadiazol-5-yl)propanamide
  • 5-oxo-N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)-1-(2-(thiophen-2-yl)ethyl)pyrrolidine-3-carboxamide
  • 1-methyl-2-oxo-N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)-1,2-dihydropyridine-3-carboxamide
  • N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)pent-4-enamide
  • 1-methyl-N-(2-(3-oxo-2,3-dihydrobenzo[f][1,4]oxazepin-4(5H)-yl)ethyl)-3-phenyl-1H-pyrazole-5-carboxamide
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