3-Fluoronitrobenzene

Suppliers

Names

[ CAS No. ]:
402-67-5

[ Name ]:
3-Fluoronitrobenzene

[Synonym ]:
1-fluoro-3-nitro benzene
3-fluoro-nitrobenzene
3-Fluoronitrobenzene
1-Fluoro-3-nitrobenzene
meta-nitrofluorobenzene
Benzene, 1-fluoro-3-nitro-
m-Nitrofluorobenzene
3-nitrofluorobenzene
m-fluoro-nitrobenzene
EINECS 206-953-0
MFCD00007196
Benzene,1-fluoro-3-nitro
3-fluoro-1-nitrobenzene

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
199.8±13.0 °C at 760 mmHg

[ Melting Point ]:
1.7ºC

[ Molecular Formula ]:
C₆H₄FNO₂

[ Molecular Weight ]:
141.100

[ Flash Point ]:
76.7±0.0 °C

[ Exact Mass ]:
141.022614

[ PSA ]:
45.82000

[ LogP ]:
1.90

[ Vapour Pressure ]:
0.5±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.534

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R23/24/25;R33

[ Safety Phrases ]:
S36/37-S45

[ RIDADR ]:
UN 2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29049085

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-Nitroaniline
1,3-Dinitrobenzene
3-Nitrophenylsulfonyl chloride
2,4-Dichloronitrobenzene
3-nitrobenzene-1-diazonium tertafluoroborate
3-Fluorobenzeneboronic acid
(4-Nitrophenyl)boronic acid
3-Nitrophenylboronic acid
3-Nitrochlorobenzene
nitrobenzene

DownStream

2-Fluoro-4-nitrophenol
2-Fluoro-6-nitrophenol
3-fluoroaniline
3,3'-difluorohydrazobenzene
4-Amino-2-fluorophenol
2-Fluoro-4-nitroaniline
4-Fluoro-2-nitroaniline
2-Fluoro-6-nitroaniline
3,4-Dinitrofluorobenzene
3-Fluoroacetanilide

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Bartoli G, et al.

J. Chem. Soc. Perkin Trans. I , 2671-2671, (1972)

Reduction of aromatic nitro compounds to aromatic amines by sodium trimethylsilanethiolate. Hwu JR, et al.

J. Org. Chem. 57(19) , 5254-55, (1992)

Design, synthesis, and evaluation of novel VEGFR2 kinase inhibitors: Discovery of [1, 2, 4] triazolo [1, 5-a] pyridine derivatives with slow dissociation kinetics. Oguro Y, et al.

Bioorg. Med. Chem. 21(15) , 4714-29, (2013)