2-Bromo-6-methoxypyridine

Names

[ CAS No. ]:
40473-07-2

[ Name ]:
2-Bromo-6-methoxypyridine

[Synonym ]:
MFCD00088345
2-Bromo-6-methoxypyridine
Pyridine, 2-bromo-6-methoxy-
2-Bromo-6-methoxy pyridine

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
205.9±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₆BrNO

[ Molecular Weight ]:
188.022

[ Flash Point ]:
78.3±21.8 °C

[ Exact Mass ]:
186.963272

[ PSA ]:
22.12000

[ LogP ]:
2.25

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.543

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Precursor & DownStream

Precursor

DownStream

2-Methoxypyridine
(2-methoxypyridin-3-yl)-trimethylsilane
6-Bromo-2-methoxynicotinic acid
6-(2,6-difluorophenyl)-1H-pyridin-2-one
6-Methoxypicolinaldehyde
2-BROMO-6-CHLOROPYRIDINE
Benzene,1-methyl-4-(phenylmethyl)-
2-methoxy-6-(4-methylbenzyl)pyridine
6-Methoxypyridine-2-carbonitrile
6-methoxypyridin-3-amin

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Efficient synthesis of aminopyridine derivatives by copper catalyzed amination reactions.

Chem. Commun. (Camb.) 46(6) , 925-7, (2010)

A copper(i) catalyzed amination reaction utilizing aqueous ammonia and operating under mild conditions is presented. This method was employed for the efficient synthesis of various aminopyridine deriv...

Synthesis and Characterization of a Family of Systematically Varied Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes.

Inorg. Chem. 37(26) , 6615-6629, (1998)

An efficient modular protocol for synthesizing a series of facial-capping tris-pyridyl ligands, based on the tris(2-pyridyl)methoxymethane backbone, has been developed which allows for systematic vari...

Synthesis of 2, 2'-Bipyridines: Versatile Building Blocks for Sexy Architectures and Functional Nanomaterials. Newkome GR, et al.

European J. Org. Chem. 2 , 235-254, (2004)