α-Acetoxy-isobutyryl bromide

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Names

[ CAS No. ]:
40635-67-4

[ Name ]:
α-Acetoxy-isobutyryl bromide

[Synonym ]:
1-Bromo-2-methyl-1-oxo-2-propanyl acetate
1-Bromo-2-methyl-1-oxopropan-2-yl acetate
Propanoyl bromide, 2-(acetyloxy)-2-methyl-
2-Acetoxyisobutyryl bromide
MFCD00040923
(1-bromo-2-methyl-1-oxopropan-2-yl) acetate
α-Acetoxy-isobutyryl bromide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
190.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H9BrO3

[ Molecular Weight ]:
209.038

[ Flash Point ]:
72.2±22.6 °C

[ Exact Mass ]:
207.973495

[ PSA ]:
43.37000

[ LogP ]:
1.42

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.469

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34;R37

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29181980

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Chloro-2-methyl-1-oxopropan-2-yl acetate
  • Propanoic acid,2-(acetyloxy)-2-methyl-

DownStream

  • 9-(2'-O-Acetyl-3'-bromo-3'-deoxy-β-D-xylofuranosyl)adenine
  • 9-(2-O-acetyl-3-bromo-3-deoxy-5-O-(2,4,4-trimethyl-5-oxo-1,3-dioxolan-2-yl)-β-D-xylofuranosyl)adenine
  • 2',3'-O-Isopropylideneadenosine
  • Stavudine
  • 1,6-Dibromo-1,6-dideoxy-D-mannitol 2,3,4,5-tetraacetate

Customs

[ HS Code ]: 2918199090

[ Summary ]:
2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Aldrichimica Acta 23 , 83, (1990)

Biphenyl dioxygenase-catalysed cis-dihydroxylation of tricyclic azaarenes: chemoenzymatic synthesis of arene oxide metabolites and furoquinoline alkaloids. Boyd DR, et al.

RSC Advances 3(27) , 10944-55, (2013)

A mild conversion of vicinal diols to alkenes. Efficient transformation of ribonucleosides into 2'-ene and 2t', 3'-dideoxynucleosides. Robins MJ, et al.

Tetrahedron Lett. 25(4) , 367-70, (1984)


More Articles

Related Compounds

  • α-acetoxyisobutyryl bromide
  • α-Acetoxyisobutyryl chloride
  • α-pinenyl bromide
  • α-bromoethyltriphenylphosphonium bromide
  • α-bromophenylacetyl bromide
  • α-terpinyl bromide
  • 3-(4-Bromo-3,5-dimethylphenyl)-2,2-dimethylpropanoic acid
  • tert-butyl N-{2-[(1R)-1-aminoethyl]-4,5-dimethoxyphenyl}carbamate
  • 2-(2-Bromo-5-methylphenyl)prop-2-enoic acid
  • 5-(2-Bromopyridin-3-yl)-1,2-oxazole-4-carboxylic acid
  • tert-butyl N-[1-amino-4-(morpholin-4-yl)butan-2-yl]carbamate
  • 2-(1-{[(Tert-butoxy)carbonyl]amino}cyclobutyl)-3-methylbutanoic acid
  • 4-(3-{[(Tert-butoxy)carbonyl]amino}-4-hydroxyphenyl)-2-methylbutanoic acid
  • Tert-butyl 3-(3-chloro-2-fluorophenyl)piperazine-1-carboxylate
  • tert-butyl 2-[1-methyl-3-(trifluoromethyl)-1H-pyrazol-5-yl]piperazine-1-carboxylate
  • 3-(5-{[(Tert-butoxy)carbonyl]amino}-2-methoxyphenyl)-1,2-oxazole-5-carboxylic acid
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