Dimethyl 2-allylmalonate

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Names

[ CAS No. ]:
40637-56-7

[ Name ]:
Dimethyl 2-allylmalonate

[Synonym ]:
MFCD00014959
dimethyl 2-allylmalonate
EINECS 255-017-8
Dimethyl allylmalonate
Propanedioic acid, 2-propenyl-, dimethyl ester
Propanedioic acid, 2-(2-propen-1-yl)-, dimethyl ester
dimethyl 2-prop-2-enylpropanedioate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
165.2±20.0 °C at 760 mmHg

[ Melting Point ]:
<-80ºC

[ Molecular Formula ]:
C8H12O4

[ Molecular Weight ]:
172.178

[ Flash Point ]:
67.3±20.2 °C

[ Exact Mass ]:
172.073563

[ PSA ]:
52.60000

[ LogP ]:
0.93

[ Vapour Pressure ]:
1.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.433

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S23-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Precursor & DownStream

Precursor

  • allyl bromide
  • Dimethyl malonate
  • Dimethyl propargylmalonate
  • Allyl acetate
  • Allyl methyl carbonate
  • Allyl tert-Butyl carbonate
  • 2-Propene-1-sulfonyl chloride
  • allyl iodide

DownStream

  • DIMETHYL 2-ALLYL-2-(PROP-2-YN-1-YL)MALONATE
  • Dimethyl 3-cyclopentene-1,1-dicarboxylate
  • dimethyl 2-(3-methylbut-2-enyl)-2-prop-1-enylpropanedioate
  • 4,4-dicarbomethoxy-3,3-dimethyl-1,6-heptadiene
  • Dimethyl propylmalonate
  • dimethyl 2,2-bis(prop-2-enyl)propanedioate
  • dimethyl 6,7-dihydro-3-methyl-7-methylene-1,4-diphenylisobenzofuran-5,5(4H)dicarboxylate
  • dimethyl 2-buta-2,3-dienyl-2-prop-1-enylpropanedioate
  • dimethyl 2-[3-(4-chlorophenyl)prop-2-enyl]propanedioate
  • 2-Vinylcyclopropane-1,1-dicarboxylic acid dimethyl ester

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Tandem cyclization/hydrosilylation of functionalized 1, 6-dienes catalyzed by a cationic palladium complex. Widenhoefer RA and DeCarli MA.

J. Am. Chem. Soc. 120(15) , 3805-3806, (1998)

Synthesis of substituted cyclopentenes from the Baylis-Hillman adducts via ring-closing metathesis reaction. Lee KY, et al.

Bull. Korean Chem. Soc. 25(8) , 1280-1282, (2004)

The study of intramolecular free radical cyclizations of a-sulfonyl and a-sulfinyl radicals. Yeun-Min T, et al.

Tetrahedron Lett. 31(42) , 6047-6050, (1990)


More Articles

Related Compounds

  • dimethyl 2-allylmalonate-d
  • dimethyl-(2-oxocyclohexyl)-prop-2-ynylazanium
  • dimethyl 2-pentadecyl-1,3-dioxolane-4,5-dicarboxylate
  • dimethyl 2,4-dimethyl-6-oxocyclohex-4-ene-1,3-dicarboxylate
  • dimethyl 2-(2-methylpyrimidin-4-yl)propanedioate
  • dimethyl-(2-nitro-[1]naphthyl)-amine