Methyl 5-chloro-2-hydroxybenzoate

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Names

[ CAS No. ]:
4068-78-4

[ Name ]:
Methyl 5-chloro-2-hydroxybenzoate

[Synonym ]:
Salicylic acid, 5-chloro-, methyl ester
MFCD00016461
Benzoic acid, 5-chloro-2-hydroxy-, methyl ester
Methyl 5-chloro-2-hydroxybenzoate
EINECS 223-778-5
Salicylic acid, 5-chloro-, methyl ester (8CI)

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
260.5±20.0 °C at 760 mmHg

[ Melting Point ]:
46-50 °C(lit.)

[ Molecular Formula ]:
C8H7ClO3

[ Molecular Weight ]:
186.592

[ Flash Point ]:
111.4±21.8 °C

[ Exact Mass ]:
186.008377

[ PSA ]:
46.53000

[ LogP ]:
3.24

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918290000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 5-chlorosalicylic acid
  • Methanol
  • Methyl salicylate
  • Acetyl chloride
  • methyl iodide
  • Methyl 4-chlorobenzoate
  • Salicylic acid
  • methyl N,N-dichlorocarbamate
  • chloropicrin

DownStream

  • 5-Chlorobenzofuran-3-one
  • Methyl 5-chloro-2-cyanobenzoate
  • 4-Methyl-3-oxo-3,4-dihydro-2H-1,4-benzoxazine-8-carboxylic acid
  • Methyl 3-amino-5-chloro-2-hydroxybenzoate
  • 5-Chloro-2-hydroxy-benzoic acid hydrazide
  • 2H-1-BENZOPYRAN-2-ONE, 6-CHLORO-4-HYDROXY-3-METHYL-
  • BENZOIC ACID, 5-CHLORO-2-MERCAPTO-
  • 5-chloro-2,2-dimethyl-3H-1-benzofuran-7-carbonyl chloride
  • 5-Chloro-2-hydroxybenzyl alcohol
  • 5-Chlorosalicylamide

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

Articles

411. Some derivatives of diphenylamine and a new synthesis of N-arylanthranilic acids and of acridones. Jamison MM and Turner EE.

J. Chem. Soc. , 1954-59, (1937)

Halogenosalicylohydroxamic Acids. I. Dihalogenosalicylohydroxamic Acids. DUDA H, et al.

Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques 13(5) , 341-7, (1965)


More Articles

Related Compounds

  • methyl 5-chloro-2-hydroxybenzoate
  • (13C,2H3)Methyl 5-chloro-2-hydroxybenzoate
  • methyl 5-chloro-2-fluoro-4-hydroxybenzoate
  • Methyl 5-chloro-4-fluoro-2-hydroxybenzoate
  • methyl 5-chloro-2-oxocyclohepta[b]furan-3-carboxylate
  • methyl 5-chloro-2-[(4-nitrophenyl)carbamoylmethoxy]benzoate
  • I+/--Propylidenebenzeneacetaldehyde 2-(2,4-dinitrophenyl)hydrazone
  • 1,1,2,2,3,4,4,5,5,6-Decafluoro-3-(1,1,2,2,2-pentafluoroethyl)-6-(trifluoromethyl)cyclohexane
  • 1H-Indole-5-propanenitrile, I+/--(aminomethyl)-4-hydroxy-2-methyl-
  • Ethanone, 2-bromo-1-[3-methoxy-2,5-bis(trifluoromethyl)phenyl]-
  • 6-(Cyclopentyloxy)-N-(3,4-dichlorophenyl)-3-pyridinecarboxamide
  • 3-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-phenylbut-2-ynamido]propanoic acid
  • Piperidine, 4-[1-(3-fluorophenyl)-2,5-dimethyl-1H-pyrrol-3-yl]-
  • 5-Benzoxazolecarboxylic acid, 2-(chlorocarbonyl)-, methyl ester
  • 3-Cyclobutoxy-2-cyclopropylpropane-1-sulfonyl chloride
  • 2(1H)-Pentalenone, 4,5,6,6a-tetrahydro-1,1,4-trimethyl-, trans-
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