6-Fluoro-2-picoline

Suppliers

Names

[ CAS No. ]:
407-22-7

[ Name ]:
6-Fluoro-2-picoline

[Synonym ]:
Pyridine, 2-fluoro-6-methyl-
2-methyl-6-fluoro-pyridine
EINECS 206-980-8
6-FLUOROPICOLINE
6-fluoro-2-methylpyridine
6-Fluoro-2-picoline
T6NJ BF F1
2-fluoro-6-picoline
2-fluoro-6-methyl-pyridine
2-Fluor-6-methylpyridin
2-Fluoro-6-methylpyridine
MFCD00041226

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
140.4±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₆FN

[ Molecular Weight ]:
111.117

[ Flash Point ]:
38.7±21.8 °C

[ Exact Mass ]:
111.048424

[ PSA ]:
12.89000

[ LogP ]:
1.30

[ Vapour Pressure ]:
7.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.477

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

6-Fluoro-2-pyridinemethanol
Methyl 6-fluoropicolinate
6-Fluoro-2-pyridinecarboxamide
2-Fluoropyridine-6-carboxylic acid
2-Methoxy-6-methylpyridine
6-Fluoropyridine-2-carbonyl chloride
2-Hydrazino-6-methylpyridine
2-(Bromomethyl)-6-fluoropyridine
2-(Chloromethyl)-6-fluoropyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

The synthesis of 2-fluoro-4-and 2-fluoro-6-pyridinecarboxylic acid and derivatives. Roe A, et al.

J. Am. Chem. Soc. 71(12) , 4152-4153, (1949)

A facile preparation of fluoropyridines from aminopyridines via diazotization and fluorodediazoniation in HF or HF-pyridine solutions. Fukuhara T, et al.

J. Fluor. Chem. 38(3) , 435-438, (1988)

Efficient synthesis of pentakis-and tris (pyridine) ligands. Ünal EA, et al.

Tetrahedron Lett. 53(1) , 54-55, (2012)