(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

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Names

[ Name ]:
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

[Synonym ]:
(1S,4R)-2-Oxobornane-10-oic acid
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
(S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid
(1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
MFCD08061242
(S)-(+)-Ketopinic acid
(1S)-(+)-KETOPINIC ACID
(+)-Ketopinic acid
Bicyclo[2.2.1]heptane-1-carboxylic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
S-(+)-ketopinic acid
rac-(1S*,4R*)-2-Oxobornane-10-oic acid
(1S,4R)-Ketopinic acid
7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
313.3±25.0 °C at 760 mmHg

[ Melting Point ]:
237-239 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₄O₃

[ Molecular Weight ]:
182.216

[ Flash Point ]:
157.5±19.7 °C

[ Exact Mass ]:
182.094299

[ PSA ]:
54.37000

[ LogP ]:
0.70

[ Vapour Pressure ]:
0.0±1.4 mmHg at 25°C

[ Index of Refraction ]:
1.535

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Yan, T.-H. et al.

Tetrahedron Lett. 32 , 4959, (1991)

Calmes, M. et al.

Tetrahedron Asymmetry 5 , 817, (1994)

Deng, J. et al.

Synthesis , 963, (1991)

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