2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinan-2-one

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Names

[ Name ]:
2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinan-2-one

[Synonym ]:
2-chloro-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphinane
MFCD03425416
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-oxide
neopentylene phosphorochloridate
2-chloro-5,5-dimethyl-1,3,2
EINECS 223-831-2
5,5-dimethyl-2-oxo-2-chloro-1,3,2-dioxaphosphorinane

Chemical & Physical Properties

[ Density]:
1.28g/cm3

[ Boiling Point ]:
152.1ºC at 760mmHg

[ Melting Point ]:
97-102ºC(lit.)

[ Molecular Formula ]:
C₅H₁₀ClO₃P

[ Molecular Weight ]:
184.55800

[ Exact Mass ]:
184.00600

[ PSA ]:
45.34000

[ LogP ]:
2.40630

[ Index of Refraction ]:
1.445

[ Storage condition ]:
2-8°C

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 1759 8/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

One-flask synthesis of cyclic diguanosine monophosphate (c-di-GMP).

Curr. Protoc. Nucleic Acid Chem. Chapter 14 , Unit 14.8.1-7, (2012)

The bacterial signaling molecule, cyclic diguanosine monophosphate (c-di-GMP), plays a key role in controlling biofilm formation and pathogenic virulence, among many other functions. It has widespread...

Synthesis and antimicrobial activity of 5, 5'-dimethyl-2-oxido-[1, 3, 2]-dioxaphos-phorinane-2-yl-amino carboxylates. Babu BH, et al.

Chemistry 19(3) , 256-260, (2008)

tert-butyl (1-ethyl-3-nitro-1H-pyrazol-5-yl)carbamate
tert-butyl (5-amino-1-methyl-1H-pyrazol-3-yl)carbamate
1-Ethyl-5-nitro-1H-pyrazol-3-amine
tert-butyl (1-ethyl-5-nitro-1H-pyrazol-3-yl)carbamate
tert-butyl (5-amino-1-ethyl-1H-pyrazol-3-yl)carbamate
3-Amino-1-(2-fluoroethyl)-1H-pyrazole-4-carboxylic acid
1-Isopropyl-5-nitro-1H-pyrazole-4-carbonitrile
1-(Difluoromethyl)-3-nitro-1H-pyrazole-4-carbonitrile
1-Cyclopentyl-3-nitro-1H-pyrazole-4-carbonitrile
3-Nitro-1-(2,2,2-trifluoroethyl)-1H-pyrazole-4-carbonitrile

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