Acetic acid,2-(trimethylsilyl)-, 1,1-dimethylethyl ester

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Names

[ CAS No. ]:
41108-81-0

[ Name ]:
Acetic acid,2-(trimethylsilyl)-, 1,1-dimethylethyl ester

[Synonym ]:
(trimethylsilyl)acetic acid tert-butyl ester
tert-Butyl (Trimethylsilyl)acetate
TMSCH2CO2-t-Bu

Chemical & Physical Properties

[ Density]:
0.87g/cm3

[ Boiling Point ]:
177ºC at 760mmHg

[ Molecular Formula ]:
C9H20O2Si

[ Molecular Weight ]:
188.33900

[ Flash Point ]:
54.2ºC

[ Exact Mass ]:
188.12300

[ PSA ]:
26.30000

[ LogP ]:
2.66630

[ Index of Refraction ]:
n20/D 1.417

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
UN 3272 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • tert-Butyl acetate
  • 2-trimethylsilylethenone
  • tert-Butanol

DownStream

  • 2-Butenoic acid,3-methyl-, 1,1-dimethylethyl ester
  • TERT-BUTYL CROTONATE
  • tert-butyl 2-cyclohexylideneacetate
  • tert-butyl 3-oxo-5-phenylpent-4-enoate
  • tert-butyl 3-methylpenta-2,4-dienoate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

S.L. Hartzell et al.

Tetrahedron Lett. , 1403, (1974)

S.L. Hartzell, M.W. Rathke

Tetrahedron Lett. , 2737, (1976)

Tetrahedron Lett. , 2757, (1976)


More Articles

Related Compounds

  • Phosphorane, diethoxyphenylbis(2,2,2-trifluoroethoxy)-
  • Tris(3-methylphenyl)bis(2,2,2-trifluoroethoxy)phosphorane
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  • (R)-6-methyl-5,6-dihydropyrrolo[3,4-b]pyrrol-4(1H)-one
  • 2-cyclopropyl-N4-isopentyl-N6-methylpyrimidine-4,6-diamine
  • O-acetoxy-methyl-N-(morpholinomethyl)-salicylamide
  • 2-(2-Methyl-5-nitro-1H-imidazol-1-yl)ethyl 3-bromobenzoate
  • N1,N2,N3-Tris(2-hydroxyphenyl)-1,2,3-propanetricarboxamide
  • 1-(tert-Butyl)-1H-imidazole-4-carboxamide
  • Methyl 2-aminooxy-4-methylpentanoate;hydrochloride