Acetic acid,2-(trimethylsilyl)-, 1,1-dimethylethyl ester

Names

[ CAS No. ]:
41108-81-0

[ Name ]:
Acetic acid,2-(trimethylsilyl)-, 1,1-dimethylethyl ester

[Synonym ]:
(trimethylsilyl)acetic acid tert-butyl ester
tert-Butyl (Trimethylsilyl)acetate
TMSCH2CO2-t-Bu

Chemical & Physical Properties

[ Density]:
0.87g/cm3

[ Boiling Point ]:
177ºC at 760mmHg

[ Molecular Formula ]:
C₉H₂₀O₂Si

[ Molecular Weight ]:
188.33900

[ Flash Point ]:
54.2ºC

[ Exact Mass ]:
188.12300

[ PSA ]:
26.30000

[ LogP ]:
2.66630

[ Index of Refraction ]:
n20/D 1.417

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
UN 3272 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Chlorotrimethylsilane
tert-Butyl acetate
2-trimethylsilylethenone
tert-Butanol

DownStream

2-Butenoic acid,3-methyl-, 1,1-dimethylethyl ester
TERT-BUTYL CROTONATE
tert-butyl 2-cyclohexylideneacetate
tert-butyl 3-oxo-5-phenylpent-4-enoate
tert-butyl 3-methylpenta-2,4-dienoate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

S.L. Hartzell et al.

Tetrahedron Lett. , 1403, (1974)

S.L. Hartzell, M.W. Rathke

Tetrahedron Lett. , 2737, (1976)

Tetrahedron Lett. , 2757, (1976)

2-[2-(Chloromethyl)butyl]-5-methyl-1,3,4-thiadiazole
2-[(2R)-N-ethyl-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(1H-imidazol-4-yl)propanamido]acetic acid
3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pent-4-enamido]-4-hydroxybenzoic acid
4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2-difluoro-N-methylpropanamido]oxolane-3-carboxylic acid
4-{[3-chloro-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)phenyl]formamido}but-2-enoic acid
2-(1-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-5-methyl-1,3-thiazol-4-yl}-N-methylformamido)acetic acid
1-(2-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopropyl]acetamido}ethyl)-1H-imidazole-4-carboxylic acid
3-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopropyl]acetamido}bicyclo[2.2.1]heptane-2-carboxylic acid
({2-[1-(Chloromethyl)cyclopent-3-en-1-yl]ethoxy}methyl)benzene
4-(Chloromethyl)-4-(3-methylbutan-2-yl)cyclopent-1-ene

The content on this webpage is sourced from various professional data sources. If you have any questions or concerns regarding the content, please feel free to contact service1@chemsrc.com.