Lithium diisopropylamide

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Names

[ CAS No. ]:
4111-54-0

[ Name ]:
Lithium diisopropylamide

[Synonym ]:
2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1)
LDA
Lithium diisopropylamide
lithium diisopropylamine
Lithium diisopropylamide solution
EINECS 223-893-0
UNII-OL028KIW1I
lithium N,N-diisopropylamide
Lithium diisopropylamide,LDA
Lithium diisopropylazanide
Lithium Diisopropylamide (LDA)
lithiumdiisopropylamide
lithium diisopropyl amide
MFCD00064449
lithium di(propan-2-yl)azanide

Chemical & Physical Properties

[ Density]:
0.864 g/mL at 25 °C(lit.)

[ Boiling Point ]:
65 °C

[ Melting Point ]:
38-42ºC

[ Molecular Formula ]:
C6H14LiN

[ Molecular Weight ]:
107.123

[ Flash Point ]:
91 °F

[ Exact Mass ]:
107.128632

[ PSA ]:
3.24000

[ LogP ]:
1.56950

[ Appearance of Characters ]:
liquid | brown

[ Vapour density ]:
>1 (vs air)

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
decomposes

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H302-H304-H314-H335-H336-H351-H361f-H373-H411

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210-P231-P280-P305 + P351 + P338-P370 + P378-P422

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R14;R15;R19;R35;R51/53;R65;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S60-S61-S62-S8-S16-S23-S33-S27

[ RIDADR ]:
UN 3399 4.3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
I

[ Hazard Class ]:
4.2

[ HS Code ]:
2924199090

Precursor & DownStream

Precursor

  • 4-Picoline
  • Diethyl ether
  • 4-Fluoro-N-methoxy-N-methylbenzamide
  • DIEA
  • Diisopropylamine
  • n-Butyllithium
  • tert-Butyl acetate
  • Octanal
  • 2-hydroxypropionic acid
  • isopropylamine

DownStream

  • 4-Bromopyridine
  • 4-Bromo-3-methylpyridine
  • 3-Bromo-4-methylpyridine
  • N,N-DIISOPROPYLANILINE
  • N-Benzyl-N-isopropylpropan-2-amine
  • 2'-Fluoropropiophenone
  • (N,N-dimethylaminomethyl)trimethylgermane
  • (CH3)2NCH2Si(CH3)3
  • isopropylamine

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • lithium diisopropylamide
  • LITHIUM DIISOPROPYLAMIDE MONO(TETRAHYDROFURAN)
  • lithium diisopropylamide mono(tetrahydrofuran)
  • lithium citrate
  • lithium,trimethyl(prop-2-enyl)silane
  • lithium,aniline