TRICHLOROACETIC ANHYDRIDE

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Names

[ CAS No. ]:
4124-31-6

[ Name ]:
TRICHLOROACETIC ANHYDRIDE

[Synonym ]:
EINECS 223-925-3
(2,2,2-trichloroacetyl) 2,2,2-trichloroacetate
Perchloroacetic Anhydride
Trichloroacetic anhydride
MFCD00000793

Chemical & Physical Properties

[ Density]:
1.69 g/mL at 25 °C(lit.)

[ Boiling Point ]:
139-141 °C60 mm Hg(lit.)

[ Molecular Formula ]:
C4Cl6O3

[ Molecular Weight ]:
308.75900

[ Flash Point ]:
98-100°C/11mm

[ Exact Mass ]:
305.79800

[ PSA ]:
43.37000

[ LogP ]:
2.79660

[ Index of Refraction ]:
n20/D 1.484(lit.)

[ Stability ]:
Stable. Moisture sensitive - store under dry atmosphere. Incompatible with strong bases, strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R35

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trichloroacetic acid
  • O-acetyl S,S-dipropyl phosphorodithioite
  • Trichloroacetyl chloride
  • Dichloromethane
  • methoxyethyne
  • Diethyl ether
  • Ethoxyethyne

DownStream

  • 2-Trichloroacetylpyrrole
  • 2-[(2,2,2-trichloroacetyl)amino]acetic acid
  • 3,3-dichloro-1,4-diphenylazetidin-2-one
  • phosgene
  • 3-methyl-isatoic anhydride
  • PhSiFClOC(O)CCl3
  • Trichloroacetyl chloride
  • Dimethyl disulfide
  • (Methylsulfinyl)-trichloracetat
  • 2,2-dichloro-2-fluoroacetyl chloride

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Adsorption of chemically synthesized mussel adhesive peptide sequences containing DOPA on stainless steel.

J. Pept. Sci. 21 , 630-5, (2015)

The adsorption of proteins at solid-liquid interfaces is important in biosensor and biomaterial applications. Marine mussels affix themselves to surfaces using a highly cross-linked, protein-based adh...

[Anhydride and halogenated-anhydride trihalogenacetic acid interaction with thymidine-5'-phosphate: ways to new activating reagents in nucleotide phosphorylation reactions].

Bioorg. Khim. 29(1) , 64-74, (2003)

The interaction of thymidine 5'-phosphate with trichloroacetic anhydride, trichloroacetyl chloride, and tribromoacetyl bromide was studied in dimethylformamide and acetonitrile in the presence of tert...

Analysis of p-chloroamphetamine and a side-chain monofluorinated analogue in rat brain.

J. Pharmacol. Methods 25(2) , 147-55, (1991)

p-Chloro-alpha-fluoromethylphenylethylamine (fluoro-p-chloroamphetamine) (FpCA) has been shown in acute studies to be a less potent depletor of the neurotransmitter amine 5-hydroxytryptamine (5-HT) in...


More Articles

Related Compounds

  • chloroacetic trichloroacetic anhydride
  • TRICHLOROACETIC ACID STEARYL ESTER
  • trichloroacetic acid (4,5-dimethoxy-2-nitro-phenyl)-phenyl-methyl ester
  • trichloroacetic acid (5-dimethylamino-2-nitro-phenyl)-methyl ester
  • Trichloroacetic-2-13C acid
  • TRICHLOROACETIC ACID UNDECYL ESTER(C11)
  • Benzonitrile,2-ethoxy-6-fluoro-4-(4-morpholinyl)-
  • 6-Chloro-2-methylnicotinamide
  • tert-butyl N-(3-aminopropoxy)-N-[(tert-butoxy)carbonyl]carbamate
  • {1-[4-(Methylamino)pyrimidin-2-YL]piperidin-4-YL}(pyridin-3-YL)methanol
  • tert-butyl N-(2-aminoethoxy)carbamate
  • N-[(1,3-dimethyl-2-oxo-2,3-dihydro-1H-benzimidazol-5-yl)methyl]-6-methylpyrazolo[1,5-a]pyrimidine-3-carboxamide
  • 3-(2-Oxo-2-phenylethylthio)benzoic acid
  • (2-fluorophenyl)(2-piperidino-4,5-dihydro-1H-imidazol-1-yl)methanone
  • 4-(3-Aminoprop-1-en-1-yl)-2-methoxyphenol
  • N-Methyl-2-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide
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