(R)-Glycerol 1-(p-toluenesulfonate)

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Names

[ CAS No. ]:
41274-09-3

[ Name ]:
(R)-Glycerol 1-(p-toluenesulfonate)

[Synonym ]:
[(2R)-2,3-dihydroxypropyl] 4-methylbenzenesulfonate
MFCD00270084

Chemical & Physical Properties

[ Density]:
1.351 g/cm3

[ Boiling Point ]:
463ºC at 760 mmHg

[ Melting Point ]:
54-59ºC

[ Molecular Formula ]:
C10H14O5S

[ Molecular Weight ]:
246.28000

[ Exact Mass ]:
246.05600

[ PSA ]:
92.21000

[ LogP ]:
1.13430

[ Index of Refraction ]:
1.559

[ Storage condition ]:
−20°C

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2905499000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate
  • (R)-2-BENZYLOXY-1,3-PROPANEDIOL 1- (P-TOLUENESULFONATE)
  • Tosyl chloride
  • allyl toluene-4-sulfonate
  • (R)-1-O-Acetyl-2-O-benzyl-3-tosylglycerol
  • (S)-3-(tosyloxy)propane-1,2-diyl dipropionate

DownStream

  • (±)-Glycidol
  • (R)-(-)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
  • (S)-3-Amino-1,2-propanediol

Customs

[ HS Code ]: 2905499000

[ Summary ]:
2905499000 other polyhydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Related Compounds

  • (-)(R)-glycerol-1-isovalerate
  • (-)(R)-glycerol-1-caprylate
  • (-)(R)-glycerol-1-oleyl ether-2.3-diacetate
  • [R,(-)]-3-O-Trityl-D-glycerol 1-(p-nitrobenzoate)
  • (R)-1-phenylpropan-2-yl 4-methylbenzenesulfonate
  • (R)-1-(p-Tolyl)ethanamine hydrochloride