5-CHLORO-1,10-PHENANTHROLINE

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Names

[ CAS No. ]:
4199-89-7

[ Name ]:
5-CHLORO-1,10-PHENANTHROLINE

[Synonym ]:
MFCD00004980
5-chloro-1,10-phenanthroline
EINECS 224-098-1

Chemical & Physical Properties

[ Density]:
1.375g/cm3

[ Boiling Point ]:
397.4ºC at 760mmHg

[ Melting Point ]:
124-126 °C(lit.)

[ Molecular Formula ]:
C12H7ClN2

[ Molecular Weight ]:
214.65000

[ Flash Point ]:
226.4ºC

[ Exact Mass ]:
214.03000

[ PSA ]:
25.78000

[ LogP ]:
3.43640

[ Index of Refraction ]:
1.741

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22-41

[ Safety Phrases ]:
26-39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 6-Chloro-8-quinolinamine
  • Glycerol
  • 1,10-Phenanthroline
  • 8-Nitroquinoline
  • 4-Chloro-2-nitroaniline
  • 6-Chloro-8-nitroquinoline
  • Hydrochloric acid

DownStream

  • 1,10-Phenanthroline-5,6-dione
  • 1H-1,10-phenanthrolin-5-one

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

1,10-Phenanthrolinium ionic liquid crystals.

Langmuir 27(5) , 2036-43, (2011)

The 1,10-phenanthrolinium cation is introduced as a new building block for the design of ionic liquid crystals. 1,10-Phenanthroline, 5-methyl-1,10-phenanthroline, 5-chloro-1,10-phenanthroline, and 4,7...

The effect of ancillary ligand chirality and phenanthroline functional group substitution on the cytotoxicity of platinum(II)-based metallointercalators.

J. Inorg. Biochem. 101 , 1049-1058, (2007)

Fifteen platinum(II)-based metallointercalators have been synthesised that utilise substituted 1,10-phenanthroline (phen) ligands, including 5-chloro-1,10-phenanthroline (5-Cl-phen), 5-methyl-1,10-phe...


More Articles

Related Compounds

  • Cr(5-chloro-1,10-phenanthroline)3(3+)
  • Cr(5-chloro-1,10-phenanthroline)3(2+)
  • [Os(DMSO)2(CN)2(5-chloro-1,10-phenanthroline)]
  • 5-(1,10-Phenanthroline-5-ylamino)-5-oxopentanoic acid
  • 4-chloro-[1,10]phenanthroline-3-carboxylic acid ethyl ester
  • 3-chloro-[1,10]phenanthroline
  • 5-Chloro-2-{3-[({3-cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}pyrimidine
  • 3-(Methoxymethyl)-5-[3-({[3-(trifluoromethyl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl]oxy}methyl)pyrrolidin-1-yl]-1,2,4-thiadiazole
  • 2-{3-[({3-Cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}-5-ethylpyrimidine
  • 6-[4-(6-cyclopropyl-2-methylpyrimidin-4-yl)piperazin-1-yl]-9H-purine
  • 2-[4-(6-Cyclopropyl-2-methylpyrimidin-4-yl)piperazin-1-yl]-3-methyl-3,4-dihydroquinazolin-4-one
  • 2-{3-[({3-Cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}-3-(trifluoromethyl)pyridine
  • 2-{3-[({3-Cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}-5-(trifluoromethyl)pyridine
  • 2-{3-[({3-Cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}pyrimidine-4-carbonitrile
  • 2-Cyclopropyl-4-(4-{2-methylpyrido[3,4-d]pyrimidin-4-yl}piperazin-1-yl)-6-(trifluoromethyl)pyrimidine
  • 2-{3-[({3-Cyclopropyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}oxy)methyl]pyrrolidin-1-yl}-5-(propan-2-yl)-1,3,4-thiadiazole
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