METHYL FLUOROSULFONATE

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Names

[ CAS No. ]:
421-20-5

[ Name ]:
METHYL FLUOROSULFONATE

[Synonym ]:
fluorosulfonyloxymethane
Fluorosulfuric Acid Methyl Ester
METHYL FLUOROSULFONATE
MFCD00014721
Methyl Fluorosulfate
EINECS 207-004-3
Fluorosulfonic Acid Methyl Ester

Chemical & Physical Properties

[ Density]:
1.45

[ Boiling Point ]:
93 °C

[ Melting Point ]:
-95 °C

[ Molecular Formula ]:
CH3FO3S

[ Molecular Weight ]:
114.09600

[ Flash Point ]:
10ºC

[ Exact Mass ]:
113.97900

[ PSA ]:
51.75000

[ LogP ]:
0.92790

[ Vapour Pressure ]:
57.3mmHg at 25°C

[ Index of Refraction ]:
1.363

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LP0720000
CHEMICAL NAME :
Fluorosulfuric acid, methyl ester
CAS REGISTRY NUMBER :
421-20-5
BEILSTEIN REFERENCE NO. :
1098714
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C-H3-F-O3-S
MOLECULAR WEIGHT :
114.10
WISWESSER LINE NOTATION :
WSFO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 ppm/1H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - changes in motor activity (specific assay) Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
112 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
455 mg/kg
TOXIC EFFECTS :
Skin and Appendages - corrosive (after topical exposure)

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - hamster Kidney
DOSE/DURATION :
25 ug/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 51,285,1978

Safety Information

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
3265

[ RTECS ]:
LP0720000

[ HS Code ]:
2915900090

Synthetic Route

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%


Related Compounds

  • methyl thiohypofluorite
  • methyl 4-bromo-5-hydroxyhexanoate
  • methyl (3S)-3-hydroxy-5-methylhexanoate
  • methyl 6-(2-hydroxyethoxy)hexanoate
  • methyl 6-(hydroxymethylamino)-6-sulfanylidenehexanoate
  • methyl 6-[(2-ethoxy-2-oxoethyl)amino]hexanoate
  • 1-(Bromomethyl)-2-(difluoromethyl)cyclopropane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide