(S)-(+)-2-Butanol

Suppliers

Names

[ Name ]:
(S)-(+)-2-Butanol

[Synonym ]:
(S)-(+)-sec-Butanol
butyl alcohol
EINECS 224-168-1
(2S)-2-Butanol
(S)-2-butanol
2-Butanol, (S)-
(S)-(+)-sec-Butyl alcohol
MFCD00064281
(2S)-(+)-2-Hydroxybutane
S-2-butanol
(S)-(+)-2-Butanol
D-(+)-Ethylmethylcarbinol
2-Butanol, (2S)-
butanol
2-Butanol
(2S)-Butan-2-ol
(2S)-(+)-Butan-2-ol
(S)-butan-2-ol

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
96.6±3.0 °C at 760 mmHg

[ Melting Point ]:
-114ºC

[ Molecular Formula ]:
C₄H₁₀O

[ Molecular Weight ]:
74.122

[ Flash Point ]:
26.7±0.0 °C

[ Exact Mass ]:
74.073166

[ PSA ]:
20.23000

[ LogP ]:
0.69

[ Vapour Pressure ]:
25.2±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.393

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H319-H335-H335 + H336-H336

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37;R67

[ Safety Phrases ]:
S13-S24/25-S26-S46-S7/9

[ RIDADR ]:
UN 1120

[ WGK Germany ]:
1

[ RTECS ]:
EO1750000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Butanone
1,2-EPOXYBUTANE
cis-2-butene
2-butene
(±)-2-Butanol
Methyl vinyl ketone
(S)-(−)-Propylene oxide
(R)-(-)-ethyl 2-butyl-n-pentylborinate

DownStream

(S)-(+)-1-METHYLPROPYL 4-METHYLBENZENESULFONATE
sec-butyl lactate
2-Butanone
(±)-2-Butanol
butan-2-yl sulfate
(S)-6-METHYLHEPTAN-2-OL
Isopropanol
Carbamic acid,N-phenyl-, 1-methylpropyl ester
(R)-(-)-2-Butanol

Articles

The substrate binding cavity of particulate methane monooxygenase from Methylosinus trichosporium OB3b expresses high enantioselectivity for n-butane and n-pentane oxidation to 2-alcohol.

Biotechnol. Lett. 33(11) , 2241-6, (2011)

The particulate methane monooxygenase (pMMO) of Methylosinus trichosporium OB3b oxidized n-butane and n-pentane and mainly produced (R)-2-butanol and (R)-2-pentanol that comprised 78 and 89% of the pr...

Interplay of metalloligand and organic ligand to tune micropores within isostructural mixed-metal organic frameworks (M'MOFs) for their highly selective separation of chiral and achiral small molecules.

J. Am. Chem. Soc. 134(20) , 8703-10, (2012)

Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both ...

Complex suicide by ethanol intoxication and inhalation of fire fumes in an old lady: interdisciplinary elucidation including post-mortem analysis of congener alcohols.

Forensic Sci. Int. 209(1-3) , e11-5, (2011)

An 88-year-old woman committed suicide by drinking a toxic amount of highly concentrated alcohol and setting two rooms of her flat on fire. As there was not enough oxygen, the fire went out, however. ...