4-Chloro-2-methylquinoline

Names

[ Name ]:
4-Chloro-2-methylquinoline

[Synonym ]:
4-Chloro-2-methylquinoline
T66 BNJ C1 EG
EINECS 224-300-8
MFCD00006757
4-Chloroquinaldine
Quinoline, 4-chloro-2-methyl-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
269.5±0.0 °C at 760 mmHg

[ Melting Point ]:
39 °C

[ Molecular Formula ]:
C₁₀H₈ClN

[ Molecular Weight ]:
177.630

[ Flash Point ]:
140.2±7.4 °C

[ Exact Mass ]:
177.034531

[ PSA ]:
12.89000

[ LogP ]:
3.24

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.635

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Methyl-4-quinolinol
4-Chloroquinoline
METHYLLITHIUM
sodium carbonate
N,N-Dimethylformamide
4-HYDROXY-2-METHYLQUINOLINE
Ethyl 3-anilinocrotonate
Quinoline, 2-methyl-,1-oxide

DownStream

2-Methyl-4-quinolinol
4-HYDRAZINYL-2-METHYLQUINOLINE
quindecamine
Quinaldine
2-methyl-4-(2-methylquinolin-4-yl)quinoline
2-methylquinoline-4-carbonitrile
2-METHYL-4-(PIPERAZIN-1-YL)QUINOLINE
4-CHLOROQINOLINE-2-CARBOXALDEHYDE
2-CYANO-3-(2-NITROPHENYL)ACRYLAMIDE
4-HYDROXY-2-METHYLQUINOLINE

Customs

[ HS Code ]: 2933499090

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

208. The reaction between phenylhydrazine and 4-chloroquinoline derivatives, and the preparation of the corresponding 4-benzeneazo-and 4-amino-compounds. Backeberg OG.

J. Chem. Soc. , 1083-1087, (1938)

4-chloro-2-methylquinoline
4-chloro-2-methylquinoline-8-ol
4-CHLORO-2-METHYLQUINOLINE OXIDE
3-Bromo-4-chloro-2-methylquinoline
8-Bromo-4-chloro-2-methylquinoline
6-BROMO-4-CHLORO-2-METHYLQUINOLINE
5-Cyclohexyl-1-oxa-4-azaspiro[5.5]undecane
5-Cyclobutyl-1-oxa-4-azaspiro[5.5]undecane
5-(Methoxymethyl)-1-oxa-4-azaspiro[5.7]tridecane
5-(Cyclobutylmethyl)-1-oxa-4-azaspiro[5.7]tridecane
4,4-Difluoro-1-[4-(hydroxymethyl)piperidin-4-yl]cyclohexan-1-ol
Tert-butyl 3-(hydroxymethyl)-3-(3-hydroxyoxetan-3-yl)pyrrolidine-1-carboxylate
7-Ethyl-5-(pentan-3-yl)-1-oxa-4-azaspiro[5.5]undecane
5-[(Propan-2-yloxy)methyl]-1-oxa-4-azaspiro[5.7]tridecane
3,3-Difluoro-1-(methoxymethyl)cyclohexan-1-amine
1-Methyl-10-(2,2,3,3-tetrafluoropropyl)-6-oxa-2-thia-9-azaspiro[4.5]decane

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