4-Morpholinamine

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Names

[ Name ]:
4-Morpholinamine

[Synonym ]:
morpholin-4-ylamine
N-Aminomorpholine
EINECS 224-347-4
Morpholine,4-amino
1-aminomorpholine
4-Morpholinamine
MFCD00006174
4-amino-morpholin
morpholin-4-amine
morpholine, 4-amino-
4-Aminomonpholine
4-Aminomorpholine
4-Morpholinamine (9CI)
N-amino-morpholine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
168.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₁₀N₂O

[ Molecular Weight ]:
102.135

[ Flash Point ]:
58.3±0.0 °C

[ Exact Mass ]:
102.079315

[ PSA ]:
38.49000

[ LogP ]:
-1.83

[ Vapour Pressure ]:
1.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.477

[ Water Solubility ]:
miscible

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QD7300000

CHEMICAL NAME :: Morpholine, 4-amino-

CAS REGISTRY NUMBER :: 4319-49-7

BEILSTEIN REFERENCE NO. :: 0103145

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H10-N2-O

MOLECULAR WEIGHT :: 102.16

WISWESSER LINE NOTATION :: T6N DOTJ AZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 3 umol/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 91,199,1981

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S23-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
QD7300000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29349990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

morpholine
4-Nitrosomorpholine
Bis(chloroethyl) ether
Water
2,2'-hydrazonobisethanol
4-NITRO MORPHOLINE
acetic acid
Ethanol
Hydrazine hydrate

DownStream

Methyl(diphenyl)silane
1-[bis(diphenylmethylsilyl)amino]morpholine
3-MORPHOLINOSYDNONIMINE
4-methyl-N-morpholin-4-ylbenzenesulfonamide
N-(1-(2-(5-Nitro-2-thienyl)-4-thiazolyl)ethylidene)-4-morpholinamine
4-Morpholinamine,N-[[2-(5-nitro-2-thienyl)-4-thiazolyl]methylene]-
N-morpholin-4-yl-1-[2-(5-nitrofuran-2-yl)-1,3-thiazol-4-yl]methanimine
NCI 143-447
N-morpholin-4-yl-5-nitro-thiophene-2-carboxamide
methyl N-morpholin-4-ylcarbamodithioate

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%