(Benzoyloxy)(tributyl)stannane

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Names

[ Name ]:
(Benzoyloxy)(tributyl)stannane

[Synonym ]:
(Benzoyloxy)tributylstannan
Stannane,benzoyloxytributyl
Stannane, (benzoyloxy)tributyl-
MFCD00078009
Tin,(benzoyloxy)tributyl
Benzoyloxytributylstannane
Tri-n-butyltin benzoate
benzoic acid, tributylstannyl ester
Tris(n-butyl)tin benzoate
(Benzoyloxy)-tributylzinn
Biomet 11
Tributylzinnbenzoat-(butyl-1-14C)
EINECS 224-399-8
(Benzoyloxy)(tributyl)stannane
(benzoyloxy)tributyltin
Caswell No. 867AA
TRIBUTYLTIN BENZOATE

Chemical & Physical Properties

[ Density]:
1.193 g/mL at 25 °C(lit.)

[ Boiling Point ]:
403.4±28.0 °C at 760 mmHg

[ Melting Point ]:
16-18ºC

[ Molecular Formula ]:
C₁₉H₃₂O₂Sn

[ Molecular Weight ]:
411.166

[ Flash Point ]:
197.7±24.0 °C

[ Exact Mass ]:
412.142426

[ PSA ]:
26.30000

[ LogP ]:
10.09

[ Appearance of Characters ]:
Liquid

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.5182

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WH6710000

CHEMICAL NAME :: Stannane, benzoyloxytributyl-

CAS REGISTRY NUMBER :: 4342-36-3

LAST UPDATED :: 199712

DATA ITEMS CITED :: 31

MOLECULAR FORMULA :: C19-H32-O2-Sn

MOLECULAR WEIGHT :: 411.20

WISWESSER LINE NOTATION :: 4-SN-4&4&OVR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 132 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 19,934,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 503 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 19,934,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 108 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ATXKA8 Archiv fuer Toxikologie. (Berlin, Fed. Rep. Ger.) V.15-31, 1954-74. For publisher information, see ARTODN. Volume(issue)/page/year: 23,283,1968

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 178 mg/kg

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00090 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 4,61,1973 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 ppm (0.05 mg/m3) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ORGANOTIN COMPOUND-air:10H TWA 0.1 mg(Sn)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Hazard Codes ]:
T;N

[ Risk Phrases ]:
R21;R25;R36/38;R48/23/25;R50/53

[ Safety Phrases ]:
S35;S45;S60;S61;S36/S37/S39

[ RIDADR ]:
UN 2788

[ WGK Germany ]:
3

[ RTECS ]:
WH6710000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2916310090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2916310090

[ Summary ]:
2916310090 other benzoic acid and its salts and esters。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Related Compounds

benzylsulfanyl(tributyl)stannane
benzenesulfinylmethyl(tributyl)stannane
benzhydryl(tributyl)stannane
benzenesulfonylmethyl(tributyl)stannane
3-bromopropyl(tributyl)stannane
3-bromopropoxy(tributyl)stannane
tert-butyl N-[1-(6-methylpyridin-3-yl)-2-oxoethyl]carbamate
Methyl 6-(1-{[(tert-butoxy)carbonyl](methyl)amino}-2-oxoethyl)pyridine-3-carboxylate
(1-{[2-Fluoro-4-(trifluoromethyl)phenyl]methyl}cyclopropyl)methanamine
methyl (3R)-3-hydroxy-3-(3-methoxy-1,2-oxazol-5-yl)propanoate
3-[2-(Propan-2-yl)-1,3-thiazol-4-yl]prop-2-en-1-amine
3-[(5,6-Dichloropyridin-3-yl)oxy]propan-1-amine
4-methoxy-N,N-dimethyl-5-(1H-pyrazol-4-yl)-1,3-thiazol-2-amine
1-(2-{4-chloro-7H-pyrrolo[2,3-d]pyrimidin-5-yl}ethyl)cyclopropan-1-amine
tert-butyl N-[1-(1-tert-butyl-1H-pyrazol-4-yl)-2-oxoethyl]-N-methylcarbamate
rac-(1R,2R)-2-(3-chlorothiophen-2-yl)cyclopropane-1-carboxylic acid

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