Monomethyl phthalate

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Names

[ CAS No. ]:
4376-18-5

[ Name ]:
Monomethyl phthalate

[Synonym ]:
1,2-Benzenedicarboxylic acid, monomethyl ester
Phthalic acid methyl ester
2-methoxycarbonylbenzoic acid
2-(Methoxycarbonyl)benzoic acid
Monomethyl phthalate
METHYL HYDROGEN PHTHALATE
phthalic acid, mono-methyl ester
MFCD00002466
1,2-Benzenedicarboxylic acid monomethyl ester
EINECS 224-476-6
Phthalic acid monomethyl ester
mono-Methyl phthalate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
328.9±25.0 °C at 760 mmHg

[ Melting Point ]:
82-84 °C(lit.)

[ Molecular Formula ]:
C9H8O4

[ Molecular Weight ]:
180.157

[ Flash Point ]:
134.7±16.7 °C

[ Exact Mass ]:
180.042252

[ PSA ]:
63.60000

[ LogP ]:
1.13

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.556

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Dimethyl phthalate
  • Carbon dioxide
  • Methyl 2-iodobenzoate
  • phthalic acid 1-tert-butyl ester 2-methyl ester
  • Benzyl methyl phthalate
  • Methanol
  • Phthalic anhydride
  • Methyl 2-formylbenzoate
  • Sodium Methylate
  • (Z)-1-morpholino-2-phthalimido-diazen-1-oxid

DownStream

  • (-)-LUPININE
  • Phthalic anhydride
  • Methyl trifluoroacetate
  • Phthalic acid
  • Methyl 2-carbamoylbenzoate
  • Methyl 2-formylbenzoate
  • 2,5-DIOXOPYRROLIDIN-1-YL METHYL PHTHALATE
  • N-Phthaloyl-L-phenylalanine
  • imino-[2-(2-methoxycarbonylphenyl)-2-oxo-ethylidene]azanium
  • 2-Phenyl-isoindole-1,3-dione

Articles

Feasibility of ultra-high performance liquid and gas chromatography coupled to mass spectrometry for accurate determination of primary and secondary phthalate metabolites in urine samples.

Anal. Chim. Acta 853 , 625-36, (2014)

Phthalates (PAEs) are ubiquitous toxic chemical compounds. During the last few years, some phthalate metabolites (MPAEs) have been proposed as appropriate biomarkers in human urine samples to determin...

Monitoring of PAEMs and beta-agonists in urine for a small group of experimental subjects and PAEs and beta-agonists in drinking water consumed by the same subjects.

J. Hazard. Mater. 277 , 169-79, (2014)

This 5-month study contains two parts: (1) to monitor the concentrations of 11 phthalate esters metabolites (PAEMs) and two beta-agonists in human urine samples collected from a small group of consent...

Phthalate Metabolites in Urine Samples from School Children in Taipei, Taiwan.

Arch. Environ. Contam. Toxicol. 69 , 202-7, (2015)

In 2011, Taiwan authorities reported that two phthalates, including di-(2-ethylhexyl) phthalate and di-iso-nonyl phthalate, were intentionally introduced into a variety of foods and beverages during t...


More Articles

Related Compounds

  • Monomethyl Phthalate-d4
  • Monomethyl Phthalate O-β-D-Glucuronide
  • monomethyl adenosine 2'-monophosphate
  • monomethyl 2-acetoxy-2-(9-xanthenyl)malonate
  • MONOMETHYL (ETHYLENE GLYCOL)PROPYLTRICHLOROSILANE
  • monomethyl (3-aminophenyl)phosphonate
  • 1-(3,3-Dimethylcyclohexyl)-2,2-difluoroethan-1-ol
  • [1-(1,4-dimethyl-1H-pyrazol-3-yl)cyclopropyl]methanol
  • 1-(6-Chloro-5-methylpyridin-3-yl)-2,2-difluorocyclopropane-1-carboxylic acid
  • 3,5-Difluoro-4-[(pyrrolidin-3-yl)methyl]pyridine
  • tert-butyl N-[3-amino-2-(6-chloro-5-methylpyridin-3-yl)propyl]carbamate
  • 3-(5-Hydroxy-2-nitrophenyl)-2-methoxypropanoic acid
  • 1-[3-(Methylsulfanyl)phenyl]-3-oxocyclobutane-1-carbonitrile
  • 3-(3-Chloro-4-methylthiophen-2-yl)-1,1,1-trifluoropropan-2-one
  • 5-(4-amino-1-methyl-1H-pyrazol-5-yl)thiophene-3-carbonitrile
  • 1-(1-{5H,6H,7H,8H-imidazo[1,2-a]pyridin-2-yl}cyclopropyl)ethan-1-ol
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