Morpholine-4-carbaldehyde

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Names

[ CAS No. ]:
4394-85-8

[ Name ]:
Morpholine-4-carbaldehyde

[Synonym ]:
morpholine-4-carbaldehyde
Molsidomine impurity D
EINECS 224-518-3
4-Morpholinecarboxaldehyde
MFCD00006170
4-Morpholinecarbaldehyde
4-formylmorpholine
N-Formylmorpholine

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
236.5±0.0 °C at 760 mmHg

[ Melting Point ]:
20-23 °C(lit.)

[ Molecular Formula ]:
C5H9NO2

[ Molecular Weight ]:
115.131

[ Flash Point ]:
107.0±25.4 °C

[ Exact Mass ]:
115.063332

[ PSA ]:
29.54000

[ LogP ]:
-1.30

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.548

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
SOLUBLE

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QD9694000
CHEMICAL NAME :
4-Morpholinecarboxaldehyde
CAS REGISTRY NUMBER :
4394-85-8
BEILSTEIN REFERENCE NO. :
0110293
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C5-H9-N-O2
MOLECULAR WEIGHT :
115.15
WISWESSER LINE NOTATION :
T6N DOTJ AVH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,888,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,888,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6500 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>16 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
QD9694000

[ HS Code ]:
29349990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • morpholine
  • Carbon dioxide
  • (Z)-Methanimidic acid
  • Formic Acid
  • 1-(4-morpholino)-2,2-diphenylethene
  • Morpholine,4-(2-methyl-1-propen-1-yl)-
  • 1-(4-morpholino)-2-phenylpropene
  • carbon monoxide
  • Methanol

DownStream

  • 4-Bromo-2-ethylbenzaldehyde
  • methyl (E)-3-morpholin-4-ylprop-2-enoate
  • 4-(Morpholinomethyl)benzonitrile
  • 5-Bromo-2-(trifluoromethoxy)benzaldehyde
  • 5-Fluoro-2-methoxybenzyl alcohol
  • 4-(5-fluoro-2-methoxybenzyl)morpholine
  • 4-Phenylmorpholine
  • Methanone,(2-methylphenyl)-4-morpholinyl-
  • 2-Formyl-4-(tributylstannyl)thiazole
  • N-formylmorpholine dimethylacetal

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Reaction of tertiary formamides with sulphur tetrafluoride. Direct synthesis of (trifluoromethyl) amines. Dmowski W and Kaminski M.

J. Fluor. Chem. 23(3) , 207-18, (1983)

209. A synthesis of adenine labelled with 14C. Clark VM and Kalckar HM.

J. Chem. Soc. , 1029-30, (1950)

Cyclic host having double bonds as bridging units. Paek K-S and Cram DJ.

Bull. Korean Chem. Soc. 10(6) , 569, (1989)


More Articles

Related Compounds

  • morpholine-4-carbaldehyde
  • 2-(hydroxymethyl)morpholine-4-carbaldehyde
  • 2-(3-chloro-4-hydroxyphenyl)morpholine-4-carbaldehyde
  • Morpholine, 4-[(7-ethyl-3-formyl-1H-indol-1-yl)acetyl]- (9CI)
  • Morpholine-4-propionic acid potassium salt
  • Morpholine,4-(1-cyclopropylethenyl)-
  • (R)-3-(Benzyloxy)decanoicacid
  • 1-Ethyl-3-(2-thienyl)piperazine
  • (Z)-6-methyl-2-(4-methylcyclohex-3-en-1-yl)hept-2-en-4-one
  • 2-(4'-Methyl-[1,1'-biphenyl]-4-yl)ethanamine
  • 6-(1,1-Dimethylethyl)-5,6,7,12-tetrahydrodibenz[c,f]azocine
  • 1-Cyclopropyl-3-(4-methoxyphenyl)piperazine
  • 1-Iodo-2-(pentan-2-yloxy)cyclooctane
  • 2-[3-(3-Methylphenyl)phenyl]ethan-1-amine
  • Hexahydro-1-(4-methylphenyl)-5(2H)-azocinone
  • 6-Bromo-2-chloro-3-[(3-chlorophenyl)methyl]quinoline
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