4-Aminobenzylamine

Names

[ CAS No. ]:
4403-71-8

[ Name ]:
4-Aminobenzylamine

[Synonym ]:
4-(Aminomethyl)aniline
MFCD00075513
α-Amino-p-toluidine

Chemical & Physical Properties

[ Density]:
1.078 g/mL at 25 °C(lit.)

[ Boiling Point ]:
101 °C0.05 mm Hg(lit.)

[ Melting Point ]:
37 °C

[ Molecular Formula ]:
C₇H₁₀N₂

[ Molecular Weight ]:
122.16800

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
122.08400

[ PSA ]:
52.04000

[ LogP ]:
2.00900

[ Index of Refraction ]:
n20/D 1.61(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 3259 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2921590090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Aminobenzonitrile
4-Nitrobenzaldoxime
1-(4-Nitrophenyl)methanamine hydrochloride (1:1)
n-(4-amino-benzyl)-acetamide
4-Nitrobenzonitrile
1-BENZYL-5-BROMO-1H-INDOLE
n-benzylacetamide
N-((4-NITROPHENYL)METHYL)ACETAMIDE
2-(4-nitrobenzyl)-1H-isoindole-1,3(2H)-dione
4-nitrobenzylbromide

DownStream

Benzylamine
Formamide, N-[(4-aminophenyl)methyl]- (9CI)
N-(4-formamidobenzyl)formamide
4-(N-Boc-Aminomethyl)aniline
tert-Butyl (4-N-boc-aminobenzyl)carbamate
N-[(4-acetamidophenyl)methyl]acetamide
4-Hydroxybenzylamine
4-(N-Fmoc-aminomethyl)aniline
1-BENZYL-5-BROMO-1H-INDOLE
N-(2-Aminobenzyl)benzamide

Customs

[ HS Code ]: 2921590090

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Highly sensitive electrochemical biosensor for bisphenol A detection based on a diazonium-functionalized boron-doped diamond electrode modified with a multi-walled carbon nanotube-tyrosinase hybrid film.

Biosens. Bioelectron. 74 , 830-5, (2015)

A highly sensitive electrochemical biosensor for the detection of Bisphenol A (BPA) in water has been developed by immobilizing tyrosinase onto a diazonium-functionalized boron doped diamond electrode...

Modification of carbon electrode with aryl groups having an aliphatic amine by electrochemical reduction of in situ generated diazonium cations.

Langmuir 24(16) , 8711-8, (2008)

The electrochemically induced functionalization of glassy carbon electrode by aryl groups having an aliphatic amine group was achieved by reduction of in situ generated diazonium cations in aqueous me...

Electrochemical modification of single carbon nanotubes.

Angew. Chem. Int. Ed. Engl. 41(8) , 1353-5, (2002)