(+/-)-Mandelamide

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Names

[ CAS No. ]:
4410-31-5

[ Name ]:
(+/-)-Mandelamide

[Synonym ]:
MANDELAMIDE
2-Hydroxy-2-phenylacetamid
MFCD00025495
2-HYDROXY-2-PHENYLACETAMIDE
2-Phenyl-2-hydroxyacetamide
hydroxyphenylacetamide

Chemical & Physical Properties

[ Density]:
1.246 g/cm3

[ Boiling Point ]:
345.5ºC at 760 mmHg

[ Melting Point ]:
133-137ºC(lit.)

[ Molecular Formula ]:
C8H9NO2

[ Molecular Weight ]:
151.16300

[ Flash Point ]:
162.7ºC

[ Exact Mass ]:
151.06300

[ PSA ]:
63.32000

[ LogP ]:
0.90560

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
22-36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor & DownStream

Precursor

  • Benzeneacetamide, a-hydroxy-N-(4-methoxyphenyl)-
  • Mandelonitrile
  • 3-Benzyloxy-4-phenyl-4H-1,5,2-dioxazin-6-on
  • Benzaldehyde
  • 2-(4-methylphenyl)sulfinyl-1-phenyl-ethanol
  • 2-(4-methylphenyl)sulfinyl-1-phenylethanone
  • Benzeneacetamide, alpha-oxo-
  • ethyl mandelate

DownStream

  • 4-Chlorobenzoin
  • 1-hydroxy-1-phenylacetone
  • Benzoin
  • 2-Propanone,1-hydroxy-1-phenyl-, oxime
  • 5-Phenyloxazolidine-2,4-dione
  • phenylethanolamine
  • Mandelic acid
  • 4-Dimethylaminobenzoin
  • 2-hydroxy-1-(4-methylphenyl)-2-phenylethanone
  • 1-hydroxy-1-phenylbutan-2-one

Articles

The mandelamide keto-enol system in aqueous solution. Generation of the enol by hydration of phenylcarbamoylcarbene.

J. Am. Chem. Soc. 125(1) , 187-94, (2003)

Flash photolysis of diazophenylacetamide in aqueous solution produced phenylcarbamoylcarbene, whose hydration generated a transient species that was identified as the enol isomer of mandelamide. This ...

[Molecular biology aspects of the antimicrobial effect of synthetic chemotherapeutic agents].

Z. Arztl. Fortbild. (Jena.) 76(15) , 662-6, (1982)

Catalytic asymmetric addition of dimethylzinc to alpha-ketoesters, using mandelamides as ligands.

Org. Lett. 8(7) , 1287-90, (2006)

[reaction: see text] A strategy based on the control of the electron-donating capabilities of the coordinating groups of the ligand has been applied in the catalytic asymmetric addition of organometal...


More Articles

Related Compounds

  • (+)-5-methylcyclohex-2-en-1-one
  • (+/-)-4-(2-furyl)-butan-2-ol acetate
  • (+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
  • (+)-(1R,3S,6S)-artemiseole
  • (+)-limousamine
  • (+/-)-2-bromophenyl 4-methylphenyl sulfoxide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine