6,6'-Dimethyl-2,2'-bipyridine

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Names

[ CAS No. ]:
4411-80-7

[ Name ]:
6,6'-Dimethyl-2,2'-bipyridine

[Synonym ]:
2-methyl-6-(6-methylpyridin-2-yl)pyridine
MFCD00059776
6,6'-DiMethyl-2,2'-bipyridyl
6,6'-Dimethyl-2,2'-bipyridine
6,6′-Dimethyl-2,2′-dipyridyl
6,6'-Di-2-picolyl
6,6'-Bi-2-picoline
EINECS 224-566-5
6,6'-Dimethyl-2,2'-dipyridyl

Chemical & Physical Properties

[ Density]:
1.06g/cm3

[ Boiling Point ]:
286 °C

[ Melting Point ]:
93-95 °C(lit.)

[ Molecular Formula ]:
C12H12N2

[ Molecular Weight ]:
184.23700

[ Flash Point ]:
104.9ºC

[ Exact Mass ]:
184.10000

[ PSA ]:
25.78000

[ LogP ]:
2.76040

[ Index of Refraction ]:
1.566

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DW1767000
CHEMICAL NAME :
2,2'-Bipyridine, 6,6'-dimethyl-
CAS REGISTRY NUMBER :
4411-80-7
BEILSTEIN REFERENCE NO. :
0128972
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C12-H12-N2
MOLECULAR WEIGHT :
184.26
WISWESSER LINE NOTATION :
T6NJ F1 B- BT6NJ F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
190 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TOXIA6 Toxicon. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.1- 1962- Volume(issue)/page/year: 23,815,1985

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DW1767000

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Bromo-6-methylpyridine
  • 6-Chloro-2-picoline
  • 2,6-Dichloropyridine
  • 2-Amino-6-picoline
  • 2-Bromopyridine
  • 2-Bromo-5-picoline
  • 2-Bromo-4-methylpyridine
  • Benzoxazole
  • 2-Bromo-3-methylpyridine
  • 2-Methyl-6-(tributylstannyl)pyridine

DownStream

  • 6-(6-methylpyridin-2-yl)pyridine-2-carbaldehyde
  • 6-(chloromethyl)-6'-methyl-2,2'-bipyridine
  • 6,6'-BIS(CHLOROMETHYL)-2,2'-BIPYRIDINE
  • 6,6'-bis(dichloromethyl)-2,2'-bipyridine
  • 2-methyl-6-(6-methyl-1-oxidopyridin-2-ylidene)pyridin-1-ium 1-oxide
  • 6,6'-dimethyl-2,2'-bipyridine mono-N-oxide
  • 2-(bromomethyl)-6-(6-(bromomethyl)pyridin-2-yl)pyridine
  • 2-(bromomethyl)-6-(6-methylpyridin-2-yl)pyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Complexes of Pd(II), Pt(II), Cu(II), Co(II) and Zn(II) chlorides with 6,6'-dimethyl-2,2'-dipyridyl. Newkome GR, et al.

J. Inorg. Nucl. Chem. 43(7) , 1529-1531, (1981)

6,6'-Dimethyl-2,2'-bipyridyl. Sengül A, et al.

Acta Crystallogr. C Struct. Chem. 54(5) , 661-662, (1998)

Two convenient and high-yielding preparations of 6, 6'-dimethyl-2, 2'-bipyridine by homocoupling of 6-bromopicoline. Cassol TM, et al.

Tetrahedron Lett. 41(43) , 8203-8206, (2000)


More Articles

Related Compounds

  • 4,4'-6,6'-dimethyl-2,2'-bipyridine
  • 6,6'-Dimethyl-2,2'-bipyridine-N-oxide
  • 5-Bromo-6,6'-dimethyl-2,2'-bipyridine
  • Cu(6,6'-dimethyl-2,2'-bipyridine)2(1+)
  • 6,6'-dimethyl-2,2'-bipyridine bis-N-oxide
  • 4,4'-Dibromo-6,6'-dimethyl-2,2'-bipyridine
  • 2-Methyl-1-oxo-1,2-dihydroisoquinoline-4-carbonitrile
  • (Z)-3-(m-tolyl)-2-(4-(p-tolyl)thiazol-2-yl)acrylonitrile
  • (Z)-2-(4-(4-ethoxyphenyl)thiazol-2-yl)-3-(m-tolyl)acrylonitrile
  • (Z)-2-(4-(3,4-dimethylphenyl)thiazol-2-yl)-3-(3-methoxyphenyl)acrylonitrile
  • (Z)-2-(4-(4-ethylphenyl)thiazol-2-yl)-3-(3-methoxyphenyl)acrylonitrile
  • (Z)-2-(4-(4-ethoxyphenyl)thiazol-2-yl)-3-(3-methoxyphenyl)acrylonitrile
  • (2Z)-2-[4-(3,4-dimethylphenyl)-1,3-thiazol-2-yl]-3-(4-methoxyphenyl)prop-2-enenitrile
  • (Z)-3-(2-ethoxyphenyl)-2-(4-(4-ethylphenyl)thiazol-2-yl)acrylonitrile
  • (Z)-3-(4-ethoxyphenyl)-2-(4-(4-ethylphenyl)thiazol-2-yl)acrylonitrile
  • (Z)-3-(4-(dimethylamino)phenyl)-2-(4-(3,4-dimethylphenyl)thiazol-2-yl)acrylonitrile
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