Trimethoxysilylpropanethiol

Suppliers

Names

[ CAS No. ]:
4420-74-0

[ Name ]:
Trimethoxysilylpropanethiol

[Synonym ]:
z6062
mercaptopropyl trimethoxysilane
(3-Mercaptopropyl)trimethoxysilane
3-(Trimethoxysilyl)propanethiol
MFCD00004901
kbe803
gf70
kbm803
(3-Mercaptopropyl)-Trimethoxysilane
CM8500
EINECS 224-588-5
3-(trimethoxysilyl)propane-1-thiol
az6129
3-(Trimethoxysilyl)-1-propanethiol
3-Mercaptopropyltrimethoxysilane
m8500
A 189
1-Propanethiol, 3-(trimethoxysilyl)-
(γ-Mercaptopropyl)trimethoxysilane
sh6062
γ-mercaptopropyltrimethoxysilane
3-mercaptopropyl trimethoxysilane

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
198.0±0.0 °C at 760 mmHg

[ Melting Point ]:
<-50ºC

[ Molecular Formula ]:
C6H16O3SSi

[ Molecular Weight ]:
196.340

[ Flash Point ]:
48.9±0.0 °C

[ Exact Mass ]:
196.058945

[ PSA ]:
66.49000

[ LogP ]:
1.09

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.439

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable, but moisture sensitive - may decomposes on exposure to moist air. Incompatible with water, alcohols, strong oxidizing agents, strong acids.

[ Water Solubility ]:
decomposes

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ7800000
CHEMICAL NAME :
Propanethiol, trimethoxysilyl-
CAS REGISTRY NUMBER :
4420-74-0
LAST UPDATED :
199712
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C6-H16-O3-S-Si
MOLECULAR WEIGHT :
196.37
WISWESSER LINE NOTATION :
SH3-SI-O1&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 4/2/1971 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2830 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
633 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DANKAS Doklady Akademii Nauk SSSR. Proceedings of the Academy of Sciences of the USSR. For English translation, see DBIOAM and DKBSAS. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1933- Volume(issue)/page/year: 229,1011,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5660 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1504 No. of Facilities: 27 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 81 (estimated) No. of Female Employees: 27 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H317-H411

[ Precautionary Statements ]:
P273-P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R43;R51/53

[ Safety Phrases ]:
S24/25-S36/37-S61-S57-S37-S24

[ RIDADR ]:
UN 3082 9/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
TZ7800000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
29310095

Synthetic Route

Precursor & DownStream

Precursor

  • (3-Bromopropyl)(trimethoxy)silane
  • 3-Chloropropyltrimethoxysilane
  • S-(3-trimethoxysilylpropyl) ethanethioate
  • Allyltrimethoxysilane

DownStream

  • Diethyl 1,2-hydrazinedicarboxylate
  • 3-(butyldisulfanyl)propyl-trimethoxysilane
  • 3,3,12,12-tetramethoxy-2,13-dioxa-7,8-dithia-3,12-disilatetradecane
  • kh590
  • 3-[3-(3-trimethoxysilylpropylsulfanyl)propyl]oxolane-2,5-dione
  • trimethoxy(3-trimethylsilylsulfanylpropyl)silane
  • 3-(2-ethenylsulfanylethylsulfanyl)propyl-trimethoxysilane
  • S-(3-trimethoxysilylpropyl) ethanethioate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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