(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine

Names

[ CAS No. ]:
442905-33-1

[ Name ]:
(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine

[Synonym ]:
MFCD04974235
(R)-Xylyl-P-Phos

Chemical & Physical Properties

[ Boiling Point ]:
791.1ºC at 760 mmHg

[ Melting Point ]:
190-194ºC

[ Molecular Formula ]:
C₄₆H₅₀N₂O₄P₂

[ Molecular Weight ]:
756.84800

[ Flash Point ]:
432.2ºC

[ Exact Mass ]:
756.32500

[ PSA ]:
89.88000

[ LogP ]:
8.16160

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Precursor & DownStream

Precursor

3-Bromo-2,6-dimethoxypyridine
3,5-dimethylphenylmagnesium bromide
Bis(3,5-dimethylphenyl)chlorophosphine
4-(bis(3,5-dimethylphenyl)phosphanyl)-3-bromo-2,6-dimethoxypyridine
4-bis(3,5-dimethylphenyl)phosphoryl-3-bromo-2,6-dimethoxypyridine

DownStream

Articles

P-Phos: a family of versatile and effective atropisomeric dipyridylphosphine ligands in asymmetric catalysis.

Acc. Chem. Res. 39 , 711, (2006)

This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...

tert-butyl 2-[[4-(benzenesulfonyl)-6-chloropyridin-2-yl]amino]-6,7-dihydro-4H-[1,3]thiazolo[5,4-c]pyridine-5-carboxylate
4-(2-Ethyl-4-hydroxyphenyl)-3,6-dihydro-1(2h)-pyridinecarboxylic acid 1,1-dimethylethyl ester
4-[4-(Bromomethyl)-3-methylphenyl]-1-piperidinecarboxylic acid 1,1-dimethylethyl ester
1-(6-Fluoro-2-naphthalenyl)-3-pyrrolidinecarboxylic acid
4-(4-Amino-2-ethylphenyl)-3,6-dihydro-1(2h)-pyridinecarboxylic acid 1,1-dimethylethyl ester
3-(4-Bromo-2-chlorophenoxy)oxetane
1-[(Tetrahydro-4-hydroxy-2h-pyran-4-yl)methyl]-3-pyrrolidinecarboxylic acid
1-(5-Chloropyridin-2-yl)pyrrolidine-3-carboxylic acid
1-[2-(4-Chlorophenyl)ethyl]-3-azetidinecarboxylic acid methyl ester
Methyl 1-((4-hydroxytetrahydro-2H-pyran-4-yl)methyl)pyrrolidine-3-carboxylate

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