2-Amino-5-bromobenzotrifluoride

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Names

[ CAS No. ]:
445-02-3

[ Name ]:
2-Amino-5-bromobenzotrifluoride

[Synonym ]:
2-Amino-5-bromobenzotrifluoride
4-bromo-2-trifluoromethylaniline
MFCD00064393
ZR DE BXFFF
4-Bromo-α,α,α-trifluoro-o-toluidine
Benzenamine, 4-bromo-2-(trifluoromethyl)-
para-bromo ortho-trifluoromethyl aniline
4-Bromo-2-(trifluoromethyl)benzenamine
EINECS 207-150-8
2-Amino-5-bromobenzo
4-Bromo-2-(trifluoromethyl)aniline
o-Toluidine, 4-bromo-α,α,α-trifluoro-
2-AMINO-5-BROMO TRIFLUOROTOLUENE

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
223.6±0.0 °C at 760 mmHg

[ Melting Point ]:
33-34ºC

[ Molecular Formula ]:
C₇H₅BrF₃N

[ Molecular Weight ]:
240.020

[ Flash Point ]:
83.7±25.9 °C

[ Exact Mass ]:
238.955734

[ PSA ]:
26.02000

[ LogP ]:
3.22

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.522

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

5-Bromo-2-nitrobenzotrifluoride
1-Trifluoromethyl-1,2-Benziodoxol-3(1H)-One
4-Bromoaniline
2-Aminobenzotrifluoride
3-Bromobenzotrifluoride
Benzotrifluoride
3-(Trifluoromethyl)aniline

DownStream

4-Bromo-2-(trifluoromethyl)benzoic acid
5-Bromo-2-iodobenzotrifluoride
N-[4-Bromo-2-(trifluoromethyl)phenyl]-2,2,2-trifluoroacetamide
N-(4-bromo-2-trifluoromethl-pheny)-Acetamide
4-Amino-3-(trifluoromethyl)benzonitrile
5-BROMO-2,3-DIAMINOBENZOTRIFLUORIDE
4-Bromo-2-nitro-6-(trifluoromethyl)aniline
4-bromo-2-chloro-6-(trifluoromethyl)aniline
4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethyl)aniline

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Some Dihalo-(trifluoromethyl)-benzenes. McBee ET, et al.

J. Am. Chem. Soc. 73(8) , 3932-34, (1951)

2-amino-5-bromopyrimidin-4-ol hydrobromide
2-Amino-5-bromobenzo[d]thiazole 3-oxide
2-Amino-5-bromo-3-ethynylpyrazine
2-Amino-5-chloropyridin-3-ol
2-Amino-5-bromo-3-piperazin-1-ylpyrazine
2-amino-5,7-dihydro-4H-thieno[2,3-c]pyran-3-carboxylic acid
1-[1-(2-Chloro-1,3-thiazol-5-yl)cyclopropyl]cyclopropan-1-amine
(3S)-3-{[(benzyloxy)carbonyl]amino}-3-(2-fluoro-4-methylphenyl)propanoic acid
2-(2-Chloro-1,3-thiazol-5-yl)ethanimidamide
(3S)-3-{[(benzyloxy)carbonyl]amino}-3-(5-chloro-2-methoxyphenyl)propanoic acid
(2S)-2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpentanamido]-4-methylpentanoic acid
3-(4-bromo-1-methyl-1H-1,2,3-triazol-5-yl)-2-hydroxypropanoic acid
3-{[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylphenyl]formamido}-2-hydroxypropanoic acid
2-(1-{[(Benzyloxy)carbonyl]amino}-octahydropentalen-1-yl)acetic acid
3-(2-Methoxy-2-oxoethyl)-4,4-dimethylhexanoic acid
4-Amino-3-(2,2-dimethyl-1,1-dioxo-1lambda6-thiolan-3-yl)butanoic acid