1-(2-Fluorophenyl)ethanone

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Names

[ CAS No. ]:
445-27-2

[ Name ]:
1-(2-Fluorophenyl)ethanone

[Synonym ]:
2'-Fluoroacetophenone
o-Fluoroacetophenone
1-[2-Fluorophenyl]ethan-1-one
2’-Fluoroacetophenone
2‘-Fluoroacetophenone
1-(2-Fluorophenyl)ethanone
1-(2-Fluorophenyl)ethan-1-one
2′-Fluoroacetophenone
2-Fluoroacetophenone
FR BV1
EINECS 207-156-0
MFCD00000320

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
180.8±0.0 °C at 760 mmHg

[ Melting Point ]:
26-27ºC

[ Molecular Formula ]:
C8H7FO

[ Molecular Weight ]:
138.14

[ Flash Point ]:
61.7±0.0 °C

[ Exact Mass ]:
138.048096

[ PSA ]:
17.07000

[ LogP ]:
1.29

[ Vapour Pressure ]:
0.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.491

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-(2-Fluorophenyl)ethanol
  • 1-(1-butoxyvinyl)-2-fluorobenzene
  • 1-Bromo-2-fluorobenzene
  • N-Butyl Vinyl Ether
  • METHYLLITHIUM
  • 2-Fluorobenzoic acid
  • 1-Fluoro-2-iodobenzene
  • Ethanoic anhydride
  • 1-(2,2-dibromovinyl)-2-fluorobenzene
  • 2-Fluorostyrene

DownStream

  • (2-fluorophenyl) acetate
  • 2-Fluorophenol
  • 3-(2-Fluorophenyl)-3-oxopropanenitrile
  • 3-Methyl-1-benzothiophene-2-carboxylic acid
  • Benzo[b]thiophene-2-carboxylicacid, 3-methyl-, methyl ester
  • 1-(2-Fluorophenyl)ethanol
  • (E)-Chalcone
  • L-1-Phenylethylamine
  • Hexaethyldisiloxane
  • triethyl(1-(2-fluorophenyl)ethoxy)silane

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Total synthesis of ascididemin via anionic cascade ring closure.

Chem. Commun. (Camb.) 48(72) , 9092-4, (2012)

A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2...

The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure. Garrett CE, et al.

Tetrahedron Asymmetry 13(13) , 1347-49, (2002)


More Articles

Related Compounds

  • Ethyl 2-methyl-5-[(2-methylprop-2-en-1-yl)oxy]-1-benzofuran-3-carboxylate
  • 4-[(2E)-2-{[1-(propan-2-yl)-1H-indol-3-yl]methylidene}hydrazinyl]benzoic acid
  • N-(4-methyl-2-thiazolyl)-3-(2-oxo-1,3-benzothiazol-3-yl)propanamide
  • Valone
  • Chaetomugilin P
  • N-{2-[2-(3-fluorophenyl)-1,3-thiazol-4-yl]ethyl}-N'-[(thiophen-2-yl)methyl]ethanediamide
  • N-(8-methyl-1-propylpyrazolo[3,4-b]quinolin-3-yl)acetamide
  • 2-[[2-(2,4-Dichlorophenoxy)acetyl]amino]-5,5,7,7-tetramethyl-4,6-dihydrothieno[2,3-c]pyridine-3-carboxamide
  • N-(1-cyclopropyl-2-oxo-3-pyridinyl)-2-[4-[[(2R)-2-hydroxypropanoyl]-methylamino]cyclohexyl]-6-methoxyindazole-5-carboxamide
  • 5-(2-Bromo-5-methoxybenzylidene)-2-thioxo-4-imidazolidinone
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