Ethyl Methylsulfonylacetate

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Names

[ CAS No. ]:
4455-15-6

[ Name ]:
Ethyl Methylsulfonylacetate

[Synonym ]:
Ethyl methylsulfonylacetate
Ethyl 2-(methylsulfonyl)acetate
Ethyl methanesulfonylacetate
EINECS 224-702-3
ethyl 2-methylsulfonylacetate
MFCD00041258

Chemical & Physical Properties

[ Density]:
1.234 g/mL at 25 °C(lit.)

[ Boiling Point ]:
111-113 °C0.2 mm Hg(lit.)

[ Molecular Formula ]:
C5H10O4S

[ Molecular Weight ]:
166.19500

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
166.03000

[ PSA ]:
68.82000

[ LogP ]:
0.67490

[ Index of Refraction ]:
n20/D 1.456(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ETHYL (METHYLTHIO)ACETATE
  • Ethanol
  • 2-(Methylsulfonyl)acetic acid
  • Sodium methanesulfinate
  • ethyl 2-bromoacetate
  • Phenylhydrazine

DownStream

  • 2-(Methylsulfonyl)acetic acid
  • ethyl 3-(methylamino)-5-phenylthiophene-2-carboxylate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Knoevenagel reaction in [MMIm][MSO₄]: synthesis of coumarins.

Molecules 16(6) , 4379-88, (2011)

The ionic liquid 1,3-dimethylimidazolium methyl sulfate, [MMIm][MSO₄], together with a small amount of water (the amount taken up by the ionic liquid upon exposure to air), acts efficiently as both so...

Yonemitsu-type condensations catalysed by proline and Eu (OTf) 3. Renzetti A, et al.

RSC Advances 4(89) , 47992-47999, (2014)

Rhodium (II)-mediated reactions of thiobenzoylketene S, N-acetals with a-diazo carbonyl compounds: synthesis of 2-substituted 3-alkylamino-5-phenylthiophenes. Song HM and Kim K.

J. Chem. Soc. Perkin Trans. I 21 , 2414-2417, (2002)


More Articles

Related Compounds

  • ethyl 2-(4-chlorophenyl)sulfonyl-2-methylsulfonylacetate
  • ethyl 2-(4-methylphenyl)sulfonyl-2-methylsulfonylacetate
  • ethyl 8-(4-fluorophenyl)-8-oxooctanoate
  • ETHYL 4-(3,4-DIMETHYLPHENYL)-4-OXOBUTYRATE
  • ETHYL 8-(1-NAPHTHYL)-8-OXOOCTANOATE
  • ethyl 3-(3-nitrophenyl)-4-oxopent-2-enoate