2-Bromo-5-fluorotoluene

Suppliers

Names

[ CAS No. ]:
452-63-1

[ Name ]:
2-Bromo-5-fluorotoluene

[Synonym ]:
1-Bromo-2-methyl-4-fluorobenzene
2-Bromo-5-fluorotolu
2-Bromo-5-flurotoluene
5-fluoro-2-bromotoluene
2-Bromo-5-fuluorotoluene
3-FLUORO-6-BROMOTOLUENE
MFCD00017921
Benzene, 1-bromo-4-fluoro-2-methyl-
2-methyl-4-fluorophenylbromide
2-BROMO-5-FULUOROTOLRENE
EINECS 207-203-5
FR DE C1
2-Bromo-5-fluoro toluene
2-Bromo-5-fluorotoluene
4-fluoro-2-methylbromobenzene
p-fluoro-o-methylphenyl bromide
1-Bromo-4-fluoro-2-methylbenzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
181.4±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H6BrF

[ Molecular Weight ]:
189.025

[ Flash Point ]:
45.0±0.0 °C

[ Exact Mass ]:
187.963684

[ LogP ]:
3.44

[ Vapour Pressure ]:
1.2±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.527

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
INSOLUBLE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S26-S36/37/39-S37/39

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Bromo-3-methylaniline
  • 3-Fluorotoluene
  • Carbon tetrachloride
  • Bromine

DownStream

  • 4-Fluoro-2-methylbenzoic acid
  • 2-Cyano-5-Fluorobenzyl Bromide
  • 2-(4-Fluoro-2-methylphenyl)acetic acid
  • 2-Bromo-5-fluorobenzoic acid
  • 4'-Fluoro-2'-methylacetophenone
  • 2-Bromo-5-fluorobenzaldehyde
  • 5-Bromo-2-fluoro-4-methylaniline
  • 4-fluoro-2-methylphenylmagnesium bromide
  • 4-Fluoro-2-methylphenylboronic acid pinacol ester
  • 4-Fluoro-2-methylbenzaldehyde

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Peri fluoro steric effects: syntheses and comparative acid-catalyzed isomerization of the 8-, 9-, and 11-fluoro-1, 2, 3, 4-tetrahydro-7, 12-dimethylbenz [a] anthracenes to exo methylene tautomers. Witiak DT, et al.

J. Org. Chem. 53(2) , 345-52, (1988)

A Concise and Efficient Synthesis of [2-Methyl-5-methylsulfonyl-4-(pyrrol-1-yl) benzoyl] guanidinium Methanesulfonate (Eniporide). Baumgarth M and Gericke R.

European J. Org. Chem. 12 , 2253-55, (2000)

2-Bromo-5-Fluorobenzoic Acid. Junhong ZYL.

Guangzhou Chemical Industry 12 , 2253-55, (2000)


More Articles

Related Compounds

  • 2-Bromo-5-chloro-3-fluorotoluene
  • 2-BROMO-4-CHLORO-5-FLUOROTOLUENE
  • 2-Bromo-3-chloro-5-fluorotoluene
  • 2-BROMO-5-CHLORO-BENZO[B]THIOPHENE
  • 2-BROMO-5-METHYLPYRIDINE 1-OXIDE
  • 2-bromo-5-(4-dimethoxy-2,6-dimethylphenyl)pyridine
  • 1-(Chloromethyl)-1-(2-methylpentyl)cyclobutane
  • 4-(4-Bromothiophen-2-yl)butan-2-ol
  • 1-(Chloromethyl)-1-(2-methylpropyl)cyclohexane
  • 1-Butyl-1-(chloromethyl)cyclohexane
  • (R)-3-Methyl-5'-nitro-spiro[imidazolidine-4,2'-indane]-2,5-dione
  • 2-(2-Methoxy-5-methylphenyl)pyrrolidine
  • 3-(1,2-Dihydro-2-oxo-3-pyridinyl)-2-propenoic acid
  • 5-Benzofurancarboxamide, N-(2-amino-1-methyl-2-thioxoethyl)-2,3-dihydro-N-methyl-
  • 1-Piperidineacetamide, 3-(aminomethyl)-N-[(4-fluoro-3-methylphenyl)methyl]-
  • 8-[(2-Methylpropan-2-yl)oxycarbonyl]-8-azabicyclo[3.2.1]octane-1-carboxylic acid
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