BICYCLO[2.2.1]HEPTANE-1-METHANESULFONYL CHLORIDE, 7,7-DIMETHYL-2-OXO-

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Names

[ CAS No. ]:
4552-50-5

[ Name ]:
BICYCLO[2.2.1]HEPTANE-1-METHANESULFONYL CHLORIDE, 7,7-DIMETHYL-2-OXO-

[Synonym ]:
camphor-10-sulfonyl chloride
DL-camphor-10-sulfonyl chloride
camphor sulfonyl chloride
10-camphorylsulfonyl chloride
MFCD00064155
camphor-10-sulfonic acid chloride
Dextro-10-camphorsulfonyl chloride
[(1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonyl chloride
L-(-)-10-Camphorsulfonyl chloride
D-CAMPHOR-10-SULFONYL CHLORIDE
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1R,4S)-
camphorsulfonic acid
(1R)-(-)-10-Camphorsulfonyl Chloride

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
349.4±15.0 °C at 760 mmHg

[ Melting Point ]:
66-68ºC(lit.)

[ Molecular Formula ]:
C10H15ClO3S

[ Molecular Weight ]:
250.742

[ Flash Point ]:
165.1±20.4 °C

[ Exact Mass ]:
250.043045

[ PSA ]:
59.59000

[ LogP ]:
1.55

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.528

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
26-27-28-36/37/39-45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

Precursor & DownStream

Precursor

  • [7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulphonic acid

DownStream

  • N-(2-hydroxy-1-methyl-2-phenylethyl)-N,7,7-trimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulphonamide
  • (1R,3S)-CYCLOPENT-4-ENE-1,3-DIOL
  • (1S)-(-)-10-MERCAPTOBORNEOL

Articles

Highly enantioselective addition of dialkylzinc reagents to ketones promoted by titanium tetraisopropoxide. Yus M, et al.

Tetrahedron Asymmetry 13(21) , 2291-93, (2002)

Asymmetric synthesis of nearly optically pure atrolactic acid methyl ether. Eliel EL and Frazee WJ.

J. Org. Chem. 44(20) , 3598-99, (1979)


More Articles

Related Compounds

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  • tert-Butyl-DL-alanine
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