TRIFLUOROMETHOXYBENZENE

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Names

[ CAS No. ]:
456-55-3

[ Name ]:
TRIFLUOROMETHOXYBENZENE

[Synonym ]:
Phenyl trifluoromethyl ether
α,α,α-Trifluoroanisole
TRIFLUOROMETHOXYBENZENE
1-(Trifluoromethoxy)benzene
MFCD00040832
Benzene, (trifluoromethoxy)-
Trifluoeomethoxybenzene
(Trifluoromethoxy)benzene
trifluoroanisole
EINECS 207-269-5
Tritluluoromethoxybenzen

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
102.8±35.0 °C at 760 mmHg

[ Melting Point ]:
-50ºC

[ Molecular Formula ]:
C₇H₅F₃O

[ Molecular Weight ]:
162.109

[ Flash Point ]:
12.2±0.0 °C

[ Exact Mass ]:
162.029251

[ PSA ]:
9.23000

[ LogP ]:
3.17

[ Vapour Pressure ]:
38.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.428

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S36/37/39-S9-S33

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Chloro-4-(trifluoromethoxy)benzene
(trichloromethoxy)benzene
4-Chlorophenol
Phenol
2,4-Dichloro-1-(trifluoromethoxy)benzene
Carbon tetrachloride
trifluoromethyl hypofluorite
benzene
S-(TRIFLUOROMETHYL)-3,7-DINITRODIBENZOTHIOPHENIUMTRIFLUOROMETHANESULFONATE

DownStream

2-Trifluoromethoxy toluene
1-Bromo-4-(trifluoromethoxy)benzene
4-Trifluoromethoxy-α,α,α-trifluoroacetophenone
1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE
4-(Trifluoromethoxy)benzyl bromide
2-(Trifluoromethoxy)phenol
2-(Trifluoromethoxy)benzaldehyde
1-Chloro-2-(trifluoromethoxy)benzene
1-Chloro-4-(trifluoromethoxy)benzene
1-Chloro-3-(trifluoromethoxy)benzene

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Chemistry in hydrogen fluoride. 7. A novel synthesis of aryl trifluoromethyl ethers. Feiring AE.

J. Org. Chem. 44(16) , 2907-2910, (1979)

Trifluoromethoxy benzene in the gas phase studied by electron diffraction and spectroscopy supplemented with ab initio calculations. Shishkov IF, et al.

J. Mol. Struct. 567 , 339-60, (2001)