2,4,6-tritert-butyl-N-methylaniline

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Names

[ Name ]:
2,4,6-tritert-butyl-N-methylaniline

[Synonym ]:
2,4,6-tri-t-butyl-N-methylaniline
N-methyl-2,4,6-tri-t-butylaniline
F0125-1774
2,4,6-Tri-t-butyl-N-methyl-anilin
GFTNLYGZUUPSSM-UHFFFAOYSA
2,4,6-Tri-tert-butyl-N-methylaniline
2,4,6-Tri-tert.-butyl-N-methylanilin

Chemical & Physical Properties

[ Density]:
0.891 g/cm3

[ Boiling Point ]:
312.2ºC at 760mmHg

[ Melting Point ]:
109-111ºC(lit.)

[ Molecular Formula ]:
C₁₉H₃₃N

[ Molecular Weight ]:
275.47200

[ Flash Point ]:
132.8ºC

[ Exact Mass ]:
275.26100

[ PSA ]:
12.03000

[ LogP ]:
5.69380

[ Index of Refraction ]:
1.501

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
20/21/22-36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

METHYLMAGNESIUM IODIDE
2,4,6-Tri-tert-butylnitrobenzene

DownStream

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Steric hindrance under high pressure. Reactions of 2, 4, 6-tri-tert-butyl-N-methylaniline with alkyl iodides. Okamoto Y and Shimizu H.

J. Am. Chem. Soc. 90(22) , 6145-6148, (1968)

Suzuki H

Electronic absorption spectra and geometry of organic molecules: An application of molecular orbital theory (Elsevier) , (2012), 485

2,4,6-tritert-butyl-N-(4-nitrophenyl)sulfanylaniline
2,4,6-tritert-butyl-N-dichloroboranylaniline
2,4,6-tritert-butyl-N-difluoroboranylaniline
2,4,6-tritert-butyl-4-hydroperoxycyclohexa-2,5-dien-1-one
2,4,6-tritert-butyl-1,1-dimethoxy-1λ5-phosphacyclohexa-1,3,5-triene
2,4,6-tritert-butyl-6-hydroperoxycyclohexa-2,4-dien-1-one
2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1,3-thiazol-4-yl]formamido}-3,3-dimethylbutanoic acid
4-chloro-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanamido]benzoic acid
2-{2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1,3-thiazol-4-yl]-N-methylacetamido}-2-methylpropanoic acid
2-{N-ethyl-2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)acetamido]acetamido}-2-methylpropanoic acid
5-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methylbutanamido]pyridine-3-carboxylic acid
5-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-3-methylbutanamido}hexanoic acid
3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-methylpentanamido]oxolane-3-carboxylic acid
3-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N,3-dimethylbutanamido]oxolane-3-carboxylic acid
(3S)-3-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)but-2-enamido]methyl}-5-methylhexanoic acid
3-cyclopropyl-2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxybutanamido]propanoic acid

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