2-(Methylamino)pyridine

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Names

[ CAS No. ]:
4597-87-9

[ Name ]:
2-(Methylamino)pyridine

[Synonym ]:
2-Pyridinamine, N-methyl-
MFCD00006250
2-(Methylamino)pyridine
EINECS 224-997-9
Pyridine, 2-(methylamino)-
2-(N-methylamino)pyridine
N-Methyl-N-(2-pyridinyl)amine
N-Methylpyridin-2-amine
2-(Methyl amino)pyridine
N-Methyl-2-pyridinamine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
201.3±13.0 °C at 760 mmHg

[ Melting Point ]:
15ºC

[ Molecular Formula ]:
C6H8N2

[ Molecular Weight ]:
108.141

[ Flash Point ]:
87.8±0.0 °C

[ Exact Mass ]:
108.068748

[ PSA ]:
24.92000

[ LogP ]:
1.07

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.579

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UT5500000
CHEMICAL NAME :
Pyridine, 2-methylamino-
CAS REGISTRY NUMBER :
4597-87-9
LAST UPDATED :
199712
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H8-N2
MOLECULAR WEIGHT :
108.16
WISWESSER LINE NOTATION :
T6NJ BM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
270 mg/kg
TOXIC EFFECTS :
Behavioral - excitement
REFERENCE :
APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 26,345,1968

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
UN2810

[ WGK Germany ]:
3

[ RTECS ]:
UT5500000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 6-bromo-N-methylpyridin-2-amine
  • pyridine oxide
  • methylamine
  • 2-pyridyllithium
  • tert-butyl N-methyl-N-pyridin-2-ylcarbamate
  • 2-Chloropyridine
  • 2-Aminopyridine
  • Formic Acid

DownStream

  • 1-(Methylamino)anthraquinone
  • 5-Bromo-N-methylpyridin-2-amine
  • 2-(Dimethylamino)pyridine
  • N-METHYL-N-(PYRIDIN-2-YL)FORMAMIDE
  • N-methyl-N-pyridin-2-ylmethanesulfonamide
  • 2-Pyridinecarboxaldehyde
  • Di-(2-picolyl)amine
  • N-methyl-N-pyridin-2-ylnitrous amide
  • Carbamodithioic acid, methyl-2-pyridinyl-, methyl ester (9CI)

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Photochemistry of 2-(methylamino) pyridine in a low-temperature argon matrix: Amino-imino tautomerism and rotational isomerism. Akai N, et al.

J. Photochem. Photobiol. A: Chem. 187(1) , 113-8, (2007)

Synthesis, characterization and demonstration of superoxide dismutase-like activity of copper (II) chloride, bromide, nitrate, thiocyanate, sulphate, and perchlorate complexes with 2-methyl-amino pyridine. Ramadan AM and El-Naggar MM.

J. Inorg. Biochem. 63(2) , 143-53, (1996)


More Articles

Related Compounds

  • 2-(Methylamino)pyridine
  • 2-(Methylamino)pyridine
  • 3-Iodo-2-(methylamino)pyridine
  • 5-amino-2-(methylamino)pyridine
  • 6-bromo-2-(methylamino)pyridine
  • 3-Ethoxy-2-(methylamino)pyridine
  • Thalidomide-5'-C3-PEG1-OH
  • 2-(4-Fluorophenyl)-6-methylpyrimidine-4-carbonitrile
  • 3-Bromo-4-(1-cyclobutylethoxy)-1lambda6-thiolane-1,1-dione
  • 2-Tert-butyl-5,6-dimethylpyrimidine-4-carbonitrile
  • 5-Ethyl-6-methyl-2-(propan-2-yl)pyrimidine-4-carbonitrile
  • 1-Bromo-5-chloro-2-methoxy-3-(nitromethyl)benzene
  • 3-(2,2,2-Trifluoroacetamido)spiro[3.3]heptane-1-carboxylic acid
  • 3-(1,3-benzothiazol-2-yl)-1-methyl-1H-pyrazol-5-amine
  • 2-Acetamido-3-ethoxybenzoic acid
  • (3S)-3-(trifluoroacetamido)hexanoic acid
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