1-Bromo-3,5-difluorobenzene

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Names

[ CAS No. ]:
461-96-1

[ Name ]:
1-Bromo-3,5-difluorobenzene

[Synonym ]:
3,5-difluoro-1-bromobenzene
4-bromo-2,6-difluorobenzene
EINECS 416-710-2
1-Bromo-3,5-difluoro benzene
1-Bromo-3,5-difluorobenzene
5-difluorobenzene
1-Bromo-3,5-difluoro
5-bromo-1,3-difluorobenzene
MFCD00010305
3,5-Difluorobromobenzene
1-bromo-3,5-difluoro-benzene
1-bromo-3,5-difluorobenene
FR CF EE
Benzene, 1-bromo-3,5-difluoro-
1-Brom-3,5-difluorbenzol

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
140.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-27 °C

[ Molecular Formula ]:
C6H3BrF2

[ Molecular Weight ]:
192.989

[ Flash Point ]:
44.4±0.0 °C

[ Exact Mass ]:
191.938614

[ LogP ]:
3.11

[ Vapour Pressure ]:
7.8±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.507

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
0.238 g/L (20 ºC)

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H317-H373-H410

[ Precautionary Statements ]:
P273-P280-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R10;R22;R38;R43;R48/22;R50/53

[ Safety Phrases ]:
S24-S36/37-S60-S61

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
2

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2903399090

Synthetic Route

Precursor & DownStream

Precursor

  • Hypophosphorous acid
  • 2-bromo-4,6-difluoroaniline hydrobromide
  • 1,3-Dibromo-5-fluorobenzene
  • 2-Bromo-4,6-difluoroaniline
  • Cuprous oxide
  • 2,4-Difluoroaniline
  • 1,3-Difluorobenzene
  • (2,6-difluorophenyl)-triethylsilane
  • (3-bromo-2,6-difluorophenyl)-triethylsilane

DownStream

  • 1,3-Difluorobenzene
  • Chlorobenzene
  • Benzonitrile
  • 3,5-Difluorobenzoic acid
  • 3,5-Difluorobenzaldehyde
  • [(3,5-Difluorophenyl)ethynyl](trimethyl)silane
  • 3-Fluoro-5-bromophenol
  • 3-(3,5-DIFLUORO-PHENYL)-PROPIONALDEHYDE
  • Dibenzyl ether
  • 3-(3,5-difluorophenyl)propanoic acid

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Regioselective ortho-lithiation of chloro and bromo substituted fluoroarenes.

Tetrahedron Lett. 37(36) , 6551-6554, (1996)


More Articles


Related Compounds

  • 1-bromo-3,5-difluorobenzene
  • 1-Bromo-3,5-difluorobenzene
  • 2-(Benzyloxy)-1-bromo-3,5-difluorobenzene
  • 1-Bromo-3-chloro-2,5-difluorobenzene
  • 1-Bromo-3-(chloromethyl)-2,5-difluorobenzene
  • 1-Bromo-3-benzyloxy-4,5-difluorobenzene
  • 2-Bromobicyclo[4.2.0]octa-1(6),2,4-trien-7-ol
  • 2-(2,5-Difluorophenyl)-2-methylcyclopropanamine
  • Methyl 2-amino-3-methyl-2-(trifluoromethyl)butanoate
  • 2-chloro-N-[(4-methyl-1,3-thiazol-5-yl)methyl]aniline
  • [1-(1,2,2,2-Tetrafluoroethyl)cyclopentyl]methanamine
  • 5-Fluoro-2-{1-[(3-hydroxypropyl)amino]ethyl}phenol
  • 3-(1-Amino-3,3-difluorocyclobutyl)phenol
  • Cyclobutyl(3-(piperazin-1-yl)azetidin-1-yl)methanone
  • 2-(1-Amino-3,3-difluorocyclobutyl)phenol
  • 5-Isopropyl-2-(trifluoromethoxy)phenyl boronic acid
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