2-fluoroethyl chloroformate

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Names

[ CAS No. ]:
462-27-1

[ Name ]:
2-fluoroethyl chloroformate

[Synonym ]:
2-Fluoroethyl chloroformate
Chloroformic acid 2-fluoroethyl ester
carbonochloridic acid,2-fluoroethyl ester(9ci)
Chlorokohlensaeure-(2-fluor-aethylester)
Formic acid,chloro-,2-fluoroethyl ester
1-Chlorcarbonyloxy-2-fluor-aethan
MFCD01726287
chlorocarbonic acid-(2-fluoro-ethyl ester)
Chlorameisensaeure-(2-flour-aethylester)
2-fluoroethyl chloridocarbonate
TL 751
2-Fluorethylester kyseliny chlormravenci [Czech]

Chemical & Physical Properties

[ Density]:
1.286g/cm3

[ Boiling Point ]:
115.5ºC at 760mmHg

[ Molecular Formula ]:
C3H4ClFO2

[ Molecular Weight ]:
126.51400

[ Flash Point ]:
51.8ºC

[ Exact Mass ]:
125.98800

[ PSA ]:
26.30000

[ LogP ]:
1.33130

[ Vapour Pressure ]:
19mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.4(lit.)

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ6300000
CHEMICAL NAME :
Formic acid, chloro-, 2-fluoroethyl ester
CAS REGISTRY NUMBER :
462-27-1
BEILSTEIN REFERENCE NO. :
1746655
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C3-H4-Cl-F-O2
MOLECULAR WEIGHT :
126.52
WISWESSER LINE NOTATION :
GVO2F

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
200 mg/kg/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
100 mg/kg/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H331

[ Precautionary Statements ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
23-34

[ Safety Phrases ]:
S26;S27;S45;S36/S37/S39

[ RIDADR ]:
UN 2742 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
LQ6300000

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • phosgene
  • 2-Fluoroethanol

DownStream

  • ethyl 2-fluoroethyl carbonate
  • Carbonic acid bis(2-fluoroethyl) ester

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Notes-Synthesis and Investigation of Organic Fluorine Compounds. XXII. The Preparation of Newer 2-Fluoroethylurethan Derivatives. Olah G, et al.

J. Org. Chem. 22(8) , 979-980, (1957)


More Articles

Related Compounds

  • 2-fluoroethyl acetate
  • 2-fluoroethyl prop-2-enoate
  • 2-fluoroethyl 2,2,3,3,3-pentafluoropropanoate
  • 2-fluoroethyl 2-(4-methoxyphenyl)acetate
  • 2-fluoroethyl 2-(4-nitrophenyl)acetate
  • 2-fluoroethyl 2-naphthalen-2-yloxyacetate