Thiophosgene
Suppliers
Names
[ CAS No. ]:
463-71-8
[ Name ]:
Thiophosgene
[Synonym ]:
MFCD00004918
thiocarbonyl chloride
Thiophosgene,AcroSeal
EINECS 207-341-6
CSCl2
Carbonothioyl dichloride
Thiophosgene
Dichlorothiocarbonyl
Carbon chlorosulfide
Thiofosgen
thiocarbonyl dichloride
Carbonothioic dichloride
Phosgene,thio
dichlorure thiocarbonyl
Thiocarbonic dichloride
Chemical & Physical Properties
[ Density]:
1.6±0.1 g/cm3
[ Boiling Point ]:
73.0±9.0 °C at 760 mmHg
[ Molecular Formula ]:
CCl2S
[ Molecular Weight ]:
114.982
[ Flash Point ]:
-2.0±18.7 °C
[ Exact Mass ]:
113.909775
[ PSA ]:
32.09000
[ LogP ]:
2.07
[ Vapour density ]:
4 (vs air)
[ Vapour Pressure ]:
126.9±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.564
[ Stability ]:
Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
[ Water Solubility ]:
slow decomposition in cold, fast in hot water
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XN2450000
- CHEMICAL NAME :
- Thiophosgene
- CAS REGISTRY NUMBER :
- 463-71-8
- BEILSTEIN REFERENCE NO. :
- 1633495
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C-Cl2-S
- MOLECULAR WEIGHT :
- 114.97
- WISWESSER LINE NOTATION :
- SUYGG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,13,1972
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,13,1972 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 929 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,13,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04557
Safety Information
[ Hazard Codes ]:
T:Toxic;
[ Risk Phrases ]:
R22;R23;R36/37/38
[ Safety Phrases ]:
S7-S9-S36/37-S45-S7/9
[ RIDADR ]:
UN 2474 6.1/PG 2
[ WGK Germany ]:
1
[ RTECS ]:
XN2450000
[ Packaging Group ]:
II
[ Hazard Class ]:
6.1(a)
[ HS Code ]:
2813900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%