(±)-Camphor

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Names

[ CAS No. ]:
464-48-2

[ Name ]:
(±)-Camphor

[Synonym ]:
Bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl-
EINECS 207-354-7
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
DL-Camphor
(1S,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
1,7,7-Trimethylbicyclo[2.2.1]-2-heptanone
(-)-Camphor
2-Keto-1,7,7-trimethylnolcamphane
Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-
(−)-Camphor,(1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
(±)-Camphor
2-Camphonone
Camphor
(1S)-camphor
(1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-
DL-2-Bornanone
MFCD00064148
L(-)-Camphor

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
207.4±0.0 °C at 760 mmHg

[ Melting Point ]:
178-180ºC

[ Molecular Formula ]:
C₁₀H₁₆O

[ Molecular Weight ]:
152.233

[ Flash Point ]:
64.4±0.0 °C

[ Exact Mass ]:
152.120117

[ PSA ]:
17.07000

[ LogP ]:
2.13

[ Vapour density ]:
5.24 (vs air)

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.485

[ Stability ]:
Stable. Incompatible with strong reducing agents, strong oxidizing agents, chlorinated solvents. Protect from direct sunlight.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EX1250000

CHEMICAL NAME :: Camphor, (1S,4S)-(-)-

CAS REGISTRY NUMBER :: 464-48-2

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H16-O

MOLECULAR WEIGHT :: 152.26

WISWESSER LINE NOTATION :: L55 A CVTJ A1 A1 B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 ug/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 1,445,1909

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 320 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02534

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F:Highlyflammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S37/39

[ RIDADR ]:
UN 2717

[ WGK Germany ]:
1

[ RTECS ]:
EX1250000

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

[ HS Code ]:
2914299000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Borneol
(+)-Borneol
(-)-Borneol
(1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one oxime
d-3-bromocamphor
tert-butyldimethyl(((1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)oxy)silane
(-)-endo-6-bromocamphor
S-(-)-3-Bromocamphor

DownStream

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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