Bufalin

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Names

[ CAS No. ]:
465-21-4

[ Name ]:
Bufalin

[Synonym ]:
3,14-dihydroxybufa-20,22-dienolide
(3β,5β)-3,14-Dihydroxybufa-20,22-dienolide
Bufalin: Bufa-20,22-dienolide, 3,14-dihydroxy-, (3b,5b)-,
Bufa-20,22-dienolide, 3,14-dihydroxy-, (3β,5β)-
5β-Bufa-20,22-dienolide, 3β,14-dihydroxy-
3β,14β-dihydroxy-5β-bufa-20,22-dienolide
(3b,5b)-3,14-Dihydroxybufa-20,22-dienolide
Bufalin
MFCD00056525

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
556.6±50.0 °C at 760 mmHg

[ Melting Point ]:
242 - 243ºC

[ Molecular Formula ]:
C24H34O4

[ Molecular Weight ]:
386.524

[ Flash Point ]:
189.0±23.6 °C

[ Exact Mass ]:
386.245697

[ PSA ]:
70.67000

[ LogP ]:
3.42

[ Vapour Pressure ]:
0.0±3.4 mmHg at 25°C

[ Index of Refraction ]:
1.594

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EI2962500
CHEMICAL NAME :
5-beta-Bufa-20,22-dienolide, 3-beta,14-dihydroxy-
CAS REGISTRY NUMBER :
465-21-4
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C24-H34-O4
MOLECULAR WEIGHT :
386.58
WISWESSER LINE NOTATION :
L E5 B666TJ A1 E1 IQ OQ F- ET6OVJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
740 ug/kg
TOXIC EFFECTS :
Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Behavioral - antipsychotic
REFERENCE :
CPBTAL Chemical and Pharmaceutical Bulletin. (Japan Pub. Trading Co., USA, 1255 Howard St., San Francisco, CA 94103) V.6- 1958- Volume(issue)/page/year: 24,1714,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
140 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ELDJ "Die Herzwirksamen Glykoside," Baumgarten, G., and W. Forster, Leipzig, Ger. Dem. Rep., VEB Georg Thieme, 1963 Volume(issue)/page/year: -,189,1963
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
137 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PAHEAA Pharmaceutica Acta Helvetiae. (Schweizerische Apothekerzeitung, Postfach 3006, CH3000 Bern, 7, Switzerland) V.1- 1926- Volume(issue)/page/year: 24,222,1949

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300

[ Precautionary Statements ]:
P264-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+: Very toxic;

[ Risk Phrases ]:
R28

[ Safety Phrases ]:
28-36/37-45

[ RIDADR ]:
UN 3462

[ WGK Germany ]:
3

[ RTECS ]:
EI2962500

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

Articles

Bufalin induces cell death in human lung cancer cells through disruption of DNA damage response pathways.

Am. J. Chin. Med. 42(3) , 729-42, (2014)

Bufalin is a key component of a Chinese medicine (Chan Su) and has been proved effective in killing various cancer cells. Its role in inducing DNA damage and the inhibition of the DNA damage response ...

Hepatitis B virus efficiently infects non-adherent hepatoma cells via human sodium taurocholate cotransporting polypeptide.

Sci. Rep. 5 , 17047, (2015)

Sodium taurocholate cotransporting polypeptide (NTCP) has been reported as a functional receptor for hepatitis B virus (HBV) infection. However, HBV could not efficiently infect HepG2 cells expressing...

Reversal effect of bufalin on multidrug resistance in K562/VCR vincristine-resistant leukemia cell line.

J. Tradit. Chin. Med. 34(6) , 678-83, (2014)

To probe insights into the reversal effect of bufalin on vincristine-acquired multidrug resistance (MDR) in human leukemia cell line K562/VCR.Proliferative inhibition rate and the reversal index (RI) ...


More Articles


Related Compounds

  • 3-oxobufalin
  • Acetylbufalin
  • Bufalin 3-sulfate
  • bufalin 3-succinate
  • Bufalin 3-suberylarginate
  • Bufalin 3-suberylarginate
  • 8-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1,7-naphthyridine-3-carboxylic acid
  • rac-(2R,3S)-2-(1-{[(9H-fluoren-9-yl)methoxy]carbonyl}pyrrolidin-3-yl)oxolane-3-carboxylic acid
  • 5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]bicyclo[2.2.1]heptane-2-carboxylic acid
  • 3-[(2S)-1-{[(9H-fluoren-9-yl)methoxy]carbonyl}-2-methylpyrrolidin-2-yl]prop-2-ynoic acid
  • 2-bromo-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-6-methoxybenzoic acid
  • 3-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopropyl]propanoic acid
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1,3-benzoxazole-4-carboxylic acid
  • 4-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-5,5,5-trifluoro-2-(trifluoromethyl)pentanoic acid
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-6-methyl-4H,5H,6H,7H-thieno[2,3-c]pyridine-3-carboxylic acid
  • 1-methyl-1H-1,2,3-benzotriazole-6-sulfonamide
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