aziprotryne

Names

[ Name ]:
aziprotryne

[Synonym ]:
4-azido-N-(1-methylethyl)-6-(methylthio)-1,3,5-triazin-2-amine
4-azido-6-(methylsulfanyl)-N-(propan-2-yl)-1,3,5-triazin-2-amine
Azeprotyrne
4-azido-N-isopropyl-6-methylthio-1,3,5-triazin-2-amine
4-azido-6-methylsulfanyl-N-propan-2-yl-1,3,5-triazin-2-amine
MFCD00078637
AZIPROTRYNE
Brasoran
aziprotryn
Mezaronil
Azirpotryne
Mesoranil
Caswell No. 063B
Mezuron
Brassoron
EINECS 225-101-9

Chemical & Physical Properties

[ Density]:
1.2855 (rough estimate)

[ Melting Point ]:
95°C

[ Molecular Formula ]:
C₇H₁₂N₇S+

[ Molecular Weight ]:
226.28200

[ Flash Point ]:
>100 °C

[ Exact Mass ]:
226.08700

[ PSA ]:
114.71000

[ LogP ]:
1.76840

[ Index of Refraction ]:
1.6000 (estimate)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XY3280000

CHEMICAL NAME :: s-Triazine, 2-azido-4-(isopropylamino)-6-(methylthio)-

CAS REGISTRY NUMBER :: 4658-28-0

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C7-H11-N7-S

MOLECULAR WEIGHT :: 225.31

WISWESSER LINE NOTATION :: T6N CN ENJ BS1 DNUNZ FMY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C195,1991

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >208 mg/m3/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,47,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2970 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Gastrointestinal - changes in structure or function of salivary glands

REFERENCE :: ESKGA2 Eisei Kagaku. Hygienic Chemistry. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) V.1- 1953- Volume(issue)/page/year: 17,310,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 265 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Behavioral - irritability Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: ESKGA2 Eisei Kagaku. Hygienic Chemistry. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) V.1- 1953- Volume(issue)/page/year: 17,310,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,26,1973

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
XY3280000

Articles

[Gas-chromatographic analysis of methylthio-containing triazines in biological substrates].

Gig. Sanit. (12) , 81-2, (1990)

Determination of s-triazines with copper and glassy carbon electrodes. Flow injection analysis of aziprotryne in water samples.

Fresenius J. Anal. Chem. 367(5) , 461-6, (2000)

The detection and determination of s-triazines, atrazine-desethyl and aziprotryne by cyclic voltammetry and an amperometric method using a metallic copper electrode and a glassy carbon electrode are d...

Oil-in-water emulsions as suitable working media for the direct polarographic determination of aziprotryne and desmetryne from its organic extracts in water samples.

Fresenius J. Anal. Chem. 367(5) , 454-60, (2000)

The electroanalytical behavior of the reduction of the herbicides aziprotryne (2-azido-4-isopropylamino-6-methylthio-1,3,5-triazine) and desmetryne (4-isopropylamino-6-methylamino-2-methylthio-1,3,5-t...