6-Chloropicolinic acid

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Names

[ CAS No. ]:
4684-94-0

[ Name ]:
6-Chloropicolinic acid

[Synonym ]:
6-Chloro-2-pyridinecarboxylic acid
6-Chloropyridine-2-carboxylic acid
MFCD00155390
6-Chloropicolinic Acid
2-Pyridinecarboxylic acid, 6-chloro-
T6NJ BVQ FG
6-Chloropyridine-2-Carboxylicacid

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
323.2±22.0 °C at 760 mmHg

[ Melting Point ]:
190-191°C

[ Molecular Formula ]:
C6H4ClNO2

[ Molecular Weight ]:
157.555

[ Flash Point ]:
149.3±22.3 °C

[ Exact Mass ]:
156.993057

[ PSA ]:
50.19000

[ LogP ]:
0.99

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.590

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TJ7535000
CHEMICAL NAME :
Picolinic acid, 6-chloro-
CAS REGISTRY NUMBER :
4684-94-0
BEILSTEIN REFERENCE NO. :
0115849
LAST UPDATED :
199712
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H4-Cl-N-O2
MOLECULAR WEIGHT :
157.56
WISWESSER LINE NOTATION :
T6NJ FVQ BG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DOEAAH Down to Earth. (Dow Chemical USA, Agricultural Products Dept., Midland, MI 48640) V.1- 1945- Volume(issue)/page/year: 32,22,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1487 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(4),52,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
777 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(4),52,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
TJ7535000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-BROMO-6-CHLOROPYRIDINE
  • Carbon dioxide
  • Formyl acetate
  • 6-Chloro-2-picoline

DownStream

  • (6-Chloro-2-pyridinyl)methanol
  • 2-Amino-6-chloropyridine
  • 2-Picolinic acid
  • 2-Chloro-6-(chloromethyl)pyridine
  • (6-Chloro-2-pyridinyl)acetonitrile
  • 6-Methoxy-3-nitropyridin-2-amin
  • Methyl 6-chloropicolinate
  • 6-Chloropyridine-2-carboxamide
  • TERT-BUTYL 6-CHLOROPICOLINATE
  • 6-Chloropyridine-2-carbaldehyde

Articles

[Determination of nitrapyrin and its metabolite 6-chloropicolinic acid in the environment].

Gig. Sanit. (4) , 52-3, (1983)

Analytical method for nitrapyrin and 6-chloropicolinic acid residues in strawberry fruit and soil.

J. Agric. Food Chem. 29(2) , 235-9, (1981)


More Articles

Related Compounds

  • 4-bromo-6-chloropicolinic acid
  • 4-BroMo-6-chloropicolinic acid
  • 4-amino-6-chloropicolinic acid
  • 3-Bromo-6-chloropicolinic acid
  • 5-Bromo-6-chloropicolinic acid
  • 5-amino-6-chloropicolinic acid
  • 3-[3-(3-fluorophenyl)-1,2,4-oxadiazol-5-yl]-1-methyl-4,5,6,7-tetrahydro-1H-pyrazolo[4,3-c]pyridine hydrochloride
  • 3-[3-(2-fluorophenyl)-1,2,4-oxadiazol-5-yl]-1-methyl-4,5,6,7-tetrahydro-1H-pyrazolo[4,3-c]pyridine hydrochloride
  • (2S,4S)-1-(Benzyloxycarbonyl)-4-hydroxypyrrolidine 2-carboxylic acid dicyclohexylammonium salt
  • N-(pyridin-2-yl)piperazine-1-carboxamide dihydrochloride
  • N-[2-(benzenesulfonamido)ethyl]prop-2-enamide
  • 2-[4-(Chloromethyl)phenyl]acetaldehyde
  • (2S)-2-(2,3-dihydro-1H-inden-2-yl)oxirane
  • 4-[4-(2-Methylpropyl)benzenesulfonyl]-3-(piperidine-1-carbonyl)quinoline
  • 6-Fluoro-3-(piperidin-1-ylcarbonyl)-4-[(4-propylphenyl)sulfonyl]quinoline
  • 2-((3-Bromopyridin-2-yl)thio)acetonitrile
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