Cineole

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Names

[ CAS No. ]:
470-82-6

[ Name ]:
Cineole

[Synonym ]:
2-Oxa-1,3,3-trimethylbicyclo(2.2.2)octane
eucalyptol (cineole)
Terpan
2-Oxabicyclo[2.2.2]octane, 1,3,3-trimethyl-
2,2,4-trimethyl-3-oxabicyclo[2.2.2]octane
Eucapur
Zineol
Eukalyptol [Czech]
p-Menthane, 1,8-epoxy-
Eucalyptol
Eucalyptole
MFCD00167977
1,8-Cineol
1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane,1,8-Cineole,1,8-Epoxy-p-menthane
EINECS 207-431-5
1,3,3-Trimethyl-2-oxabicyclo(2.2.2)octane
cineole
Cajeputol
1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane
1,8-cineole
1,8-Epoxy-p-menthane
limonene oxide
p-Cineole

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
174.0±8.0 °C at 760 mmHg

[ Melting Point ]:
1.5ºC

[ Molecular Formula ]:
C10H18O

[ Molecular Weight ]:
154.249

[ Flash Point ]:
50.9±15.3 °C

[ Exact Mass ]:
154.135757

[ PSA ]:
9.23000

[ LogP ]:
2.82

[ Vapour Pressure ]:
1.6±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.461

[ Stability ]:
Stable. Flammable. Incompatible with acids, bases, strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OS9275000
CHEMICAL NAME :
p-Menthane, 1,8-epoxy-
CAS REGISTRY NUMBER :
470-82-6
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C10-H18-O
MOLECULAR WEIGHT :
154.28
WISWESSER LINE NOTATION :
T66 A B AOTJ B1 B1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2480 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - coma
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1070 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1500 mg/kg
TOXIC EFFECTS :
Skin and Appendages - dermatitis, other (after systemic exposure)
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2250 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory stimulation
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
DOSE :
2 gm/kg
SEX/DURATION :
female 19-22 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
200 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** REVIEWS *** TOXICOLOGY REVIEW DPIRDU Dangerous Properties of Industrial Materials Report. (Van Nostrand Reinhold, 115 Fifth Ave., New York, NY 10003) V.1- 1981- Volume(issue)/page/year: 2(4),10,1982 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 19540 No. of Facilities: 1103 (estimated) No. of Industries: 11 No. of Occupations: 23 No. of Employees: 5213 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 19540 No. of Facilities: 4397 (estimated) No. of Industries: 48 No. of Occupations: 57 No. of Employees: 83399 (estimated) No. of Female Employees: 20158 (estimated)

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Precautionary Statements ]:
P210-P370 + P378

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R37/38;R41

[ Safety Phrases ]:
S26-S39

[ RIDADR ]:
UN 1993

[ WGK Germany ]:
2

[ RTECS ]:
OS9275000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.0

Synthetic Route

Precursor & DownStream

Precursor

  • 2,2,4-trimethyl-5-phenylselanyl-3-oxabicyclo[2.2.2]octane
  • 1-(2,6-dimethyl-3,4-dihydro-2H-pyran-2-yl)-ethanone
  • 1-(2,6-Dimethyl-3,4-dihydro-2H-pyran-2-yl)-2-diazo-1-ethanone
  • METHYLMAGNESIUM IODIDE
  • alpha-Terpinene
  • Terpineol
  • Limonene oxide, (-)-
  • Terpin Monohydrate
  • 1,5-Dimethyl-8-oxatricyclo[3.2.1.02.7]octan-6-one

DownStream

  • 3,6-dimethyl-4,5-dihydro-1-benzofuran
  • Piperitenone
  • UNII:LK024V9U3C
  • 1-Isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane
  • m-Xylene
  • limonene
  • 4-Isopropenyl-1-methylcyclohexanol
  • Acetone
  • Toluene

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Related Compounds

  • Cineole
  • Isocineole
  • 6-oxocineole
  • dehydrocineole
  • dehydrocineole
  • Hydroxy cineole
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • ((5-Bromo-2-nitrobenzyl)oxy)(tert-butyl)dimethylsilane
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide